Corroles at work: A small macrocycle for great applications
Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …
Milestones in corrole chemistry: historical ligand syntheses and post-functionalization
Corroles are synthetic porphyrin analogs that contain one meso carbon atom lesser and
bear a trianionic N4 metal-chelating core. They require in-depth preparative chemistry …
bear a trianionic N4 metal-chelating core. They require in-depth preparative chemistry …
Milestones and most recent advances in Corrole's Science and Technology
The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …
Silver Anniversary of the Renaissance in Metallocorrole Chemistry
The 1999 discovery of one-pot corrole synthesis opened the floodgates for research on
these unique macrocyclic chelating agents. The enormous impact of this discovery has been …
these unique macrocyclic chelating agents. The enormous impact of this discovery has been …
Diversifying the functions of heme proteins with non-porphyrin cofactors
CM Lemon - Journal of Inorganic Biochemistry, 2023 - Elsevier
Heme proteins perform diverse biochemical functions using a single iron porphyrin cofactor.
This versatility makes them attractive platforms for the development of new functional …
This versatility makes them attractive platforms for the development of new functional …
Solvent Effects on the Phosphorescence of Gold (III) Complexes Chelated by β-Multisubstituted Corroles
A set of gold corrole complexes containing four different β-substituent groups (Br/I/CF3),
namely, 4Br–Au, 4I–Au, and 4CF 3–Au, were investigated; all showed room temperature …
namely, 4Br–Au, 4I–Au, and 4CF 3–Au, were investigated; all showed room temperature …
Phosphorus corroles: Synthesis and applications
Phosphorus corroles display exceptional structural, electrochemical, and photophysical
properties, along with some tremendous chemical reactivities that are not shared by other …
properties, along with some tremendous chemical reactivities that are not shared by other …
Tailoring intersystem crossing in phosphorus corroles through axial chalcogenation: a detailed theoretical study
Intersystem crossing (ISC) of visible-light absorbing metal-free corrole macrocycles can be
greatly tuned by means of suitable chemical functionalization. Axially chalcogenated …
greatly tuned by means of suitable chemical functionalization. Axially chalcogenated …
Phosphorus Corroles: Tuning of their Photophysical and Redox Properties via Axial Ligation and Macrocycle Modification
Given the increased interest in phosphorus corroles for many applications, we now report
how their photophysical variables and redox potentials may be tuned. This was performed …
how their photophysical variables and redox potentials may be tuned. This was performed …
Synthesis, structural characterization and binding ability of A2B cobalt (III) corroles with pyridine
A series of five A 2 B type bis-pyridine ligated cobalt complexes Co [(p-NO 2 Ph) 2 RCor](py)
2, has been synthesized where R belongs to different electron withdrawing or electron …
2, has been synthesized where R belongs to different electron withdrawing or electron …