Corroles at work: A small macrocycle for great applications

C Di Natale, CP Gros, R Paolesse - Chemical Society Reviews, 2022 - pubs.rsc.org
Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …

Milestones in corrole chemistry: historical ligand syntheses and post-functionalization

A Kumar, D Kim, S Kumar, A Mahammed… - Chemical Society …, 2023 - pubs.rsc.org
Corroles are synthetic porphyrin analogs that contain one meso carbon atom lesser and
bear a trianionic N4 metal-chelating core. They require in-depth preparative chemistry …

Milestones and most recent advances in Corrole's Science and Technology

A Mahammed, Z Gross - Journal of the American Chemical …, 2023 - ACS Publications
The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …

Silver Anniversary of the Renaissance in Metallocorrole Chemistry

A Mahammed, HB Gray, Z Gross - Chemical Reviews, 2025 - ACS Publications
The 1999 discovery of one-pot corrole synthesis opened the floodgates for research on
these unique macrocyclic chelating agents. The enormous impact of this discovery has been …

Diversifying the functions of heme proteins with non-porphyrin cofactors

CM Lemon - Journal of Inorganic Biochemistry, 2023 - Elsevier
Heme proteins perform diverse biochemical functions using a single iron porphyrin cofactor.
This versatility makes them attractive platforms for the development of new functional …

Solvent Effects on the Phosphorescence of Gold (III) Complexes Chelated by β-Multisubstituted Corroles

X Zhan, W Lee, K Sudhakar, D Kim… - Inorganic …, 2021 - ACS Publications
A set of gold corrole complexes containing four different β-substituent groups (Br/I/CF3),
namely, 4Br–Au, 4I–Au, and 4CF 3–Au, were investigated; all showed room temperature …

Phosphorus corroles: Synthesis and applications

R Kubba, O Yadav, A Kumar - Journal of Molecular Structure, 2024 - Elsevier
Phosphorus corroles display exceptional structural, electrochemical, and photophysical
properties, along with some tremendous chemical reactivities that are not shared by other …

Tailoring intersystem crossing in phosphorus corroles through axial chalcogenation: a detailed theoretical study

AM Tedy, AK Manna - Physical Chemistry Chemical Physics, 2024 - pubs.rsc.org
Intersystem crossing (ISC) of visible-light absorbing metal-free corrole macrocycles can be
greatly tuned by means of suitable chemical functionalization. Axially chalcogenated …

Phosphorus Corroles: Tuning of their Photophysical and Redox Properties via Axial Ligation and Macrocycle Modification

W Sinha, N Fridman, A Mahammed… - Israel Journal of …, 2023 - Wiley Online Library
Given the increased interest in phosphorus corroles for many applications, we now report
how their photophysical variables and redox potentials may be tuned. This was performed …

Synthesis, structural characterization and binding ability of A2B cobalt (III) corroles with pyridine

N Fridman, A Kumar, SG Warkar - Inorganica Chimica Acta, 2021 - Elsevier
A series of five A 2 B type bis-pyridine ligated cobalt complexes Co [(p-NO 2 Ph) 2 RCor](py)
2, has been synthesized where R belongs to different electron withdrawing or electron …