Uranium complexes can be stabilized in a wide range of oxidation states, ranging from UII to
UVI and a very recent example of a UI complex. This review provides a comprehensive …

The chemistry of actinide-nitrides has witnessed significant advances in the last ten years
with a large focus on uranium and a few breakthroughs with thorium. Following the early …

Uranium nitrides play important roles in dinitrogen activation and functionalization and in
chemistry for nuclear fuels, but the synthesis and isolation of the highly reactive uranium (VI) …

An N-aryloxide-amidine ligand (1),[ONNO] ligand, integrating phenoxide (PhO–) and
amidine ligands through methylene linkers, was employed in actinide chemistry. Upon …

Dinitrogen cleavage provides an attractive but poorly studied route to the assembly of
multimetallic nitride clusters. Here, we show that the monoelectron reduction of the …

Pentavalent uranium compounds are key components of uranium's redox chemistry and
play important roles in environmental transport. Despite this, well‐characterized U (V) …

Isostructural trivalent lanthanide and actinide amidinates bearing the N, N'-bis (isopropyl)
benzamidinate (i Pr2BA) ligand [LnIII/AnIII (i Pr2BA) 3](Ln= La, Nd, Sm, Eu, Yb, Lu; An= U …

A double-layer N–P ligand-supported uranium azide complex 2 ([N (CH2CH2NP i Pr2)
3UN3] 2) was synthesized by the reaction of a uranium precursor [N (CH2CH2NP i Pr2) …

Treatment of [UIV (N3)(TrenTIPS)](1, TrenTIPS={N (CH2CH2NSiPri3) 3} 3−) with excess Li
resulted in the isolation of [{UIV (μ-NLi2)(TrenTIPS)} 2](2), which exhibits a diuranium …

Reactions between [(TrenTIPS) UVIN](1, TrenTIPS={N (CH2CH2NSiPri3) 3} 3−) and [MII (η5-
C5R5) 2](M/R= Cr/H, Mn/H, Fe/H, Ni/H) were intractable, but M/R= Co/H or Co/Me afforded …