Formal [4+ 1] annulation reactions in the synthesis of carbocyclic and heterocyclic systems
JR Chen, XQ Hu, LQ Lu, WJ **ao - Chemical reviews, 2015 - ACS Publications
The development of new strategies and chemical reactions continues to be a major focus of
research efforts in the modern synthetic organic community. 1 Of the various types of …
research efforts in the modern synthetic organic community. 1 Of the various types of …
Recent advances in the chemistry of conjugated nitrosoalkenes and azoalkenes
This review aims to present the most recent contributions in the chemistry of nitrosoalkenes
and azoalkenes, highlighting the chemical behavior that makes them important and versatile …
and azoalkenes, highlighting the chemical behavior that makes them important and versatile …
Formal [4+1] Annulation of Azoalkenes with CF3-Imidoyl Sulfoxonium Ylides and Dual Double Bond Isomerization Cascade: Synthesis of Trifluoromethyl-Containing …
Y Sun, Z Yang, SN Lu, Z Chen, XF Wu - Organic Letters, 2022 - ACS Publications
A straightforward strategy for the metal-free construction of trifluoromethyl-containing
pyrazole derivatives has been achieved from readily available α-halo hydrazones and CF3 …
pyrazole derivatives has been achieved from readily available α-halo hydrazones and CF3 …
N-heterocyclic carbene catalyzed switchable reactions of enals with azoalkenes: formal [4+ 3] and [4+ 1] annulations for the synthesis of 1, 2-diazepines and pyrazoles
A regio-and enantioselective formal [4+ 3] annulation reaction between enals and in situ
formed azoalkenes has been achieved. A diverse set of 1, 2-diazepine derivatives were …
formed azoalkenes has been achieved. A diverse set of 1, 2-diazepine derivatives were …
I2/TBPB Mediated Oxidative Reaction of N-Tosylhydrazones with Anilines: Practical Construction of 1,4-Disubstituted 1,2,3-Triazoles under Metal-Free and Azide …
ZJ Cai, XM Lu, Y Zi, C Yang, LJ Shen, J Li… - Organic …, 2014 - ACS Publications
An efficient I2 (20 mol%)/TBPB mediated oxidative formal [4+ 1] cycloaddition of N-
tosylhydrazones with anilines via C–N/N–N bond formation and S–N cleavage has been …
tosylhydrazones with anilines via C–N/N–N bond formation and S–N cleavage has been …
Enantioselective synthesis of multi-nitrogen-containing heterocycles using azoalkenes as key intermediates
L Wei, C Shen, YZ Hu, HY Tao, CJ Wang - Chemical Communications, 2019 - pubs.rsc.org
Chiral multi-nitrogen-containing heterocycles, such as pyrazole, imidazole and pyridazine,
are widely found in naturally occurring organic compounds and pharmaceuticals, and …
are widely found in naturally occurring organic compounds and pharmaceuticals, and …
Chemo-, regio-and enantioselective dearomative (3+ 2) reaction of non-functionalized 1-naphthols
The catalytic asymmetric dearomatization reaction of non-functionalized arenes poses a
long-standing synthetic challenge to organic chemists because of the relative ease of …
long-standing synthetic challenge to organic chemists because of the relative ease of …
Catalytic asymmetric cascade vinylogous Mukaiyama 1, 6-Michael/Michael addition of 2-silyloxyfurans with azoalkenes: direct approach to fused butyrolactones
J Li, R Huang, YK **ng, G Qiu, HY Tao… - Journal of the American …, 2015 - ACS Publications
An unprecedented cascade vinylogous Mukaiyama 1, 6-MA/MA of 2-silyloxyfurans and
azoalkenes was realized with a Cu (II)/t Bu-Box complex. An array of fused butyrolactones …
azoalkenes was realized with a Cu (II)/t Bu-Box complex. An array of fused butyrolactones …
Synthesis of 5-(trifluoromethyl) pyrazolines by formal [4+ 1]-annulation of fluorinated sulfur ylides and azoalkenes
Z Wang, Y Yang, F Gao, Z Wang, Q Luo, L Fang - Organic letters, 2018 - ACS Publications
Synthesis of 5-(Trifluoromethyl)pyrazolines by Formal [4 + 1]-Annulation of Fluorinated Sulfur
Ylides and Azoalkenes | Organic Letters ACS ACS Publications C&EN CAS Find my institution …
Ylides and Azoalkenes | Organic Letters ACS ACS Publications C&EN CAS Find my institution …
TEMPO-mediated aza-Diels–Alder reaction: Synthesis of tetrahydropyridazines using ketohydrazones and olefins
XL Yang, XX Peng, F Chen, B Han - Organic letters, 2016 - ACS Publications
A novel, facile, and efficient method for the synthesis of tetrahydropyridazines by a one-pot
tandem reaction of easily accessible ketohydrazones and olefins in the presence of 2, 2, 6, 6 …
tandem reaction of easily accessible ketohydrazones and olefins in the presence of 2, 2, 6, 6 …