Magnesia-based cements: a journey of 150 years, and cements for the future?

SA Walling, JL Provis - Chemical reviews, 2016 - ACS Publications
This review examines the detailed chemical insights that have been generated through 150
years of work worldwide on magnesium-based inorganic cements, with a focus on both …

[HTML][HTML] Solid-state nuclear magnetic resonance spectroscopy of cements

B Walkley, JL Provis - Materials Today Advances, 2019 - Elsevier
Cement is the ubiquitous material upon which modern civilisation is built, providing long-
term strength, impermeability and durability for housing and infrastructure. The fundamental …

Cemdata18: A chemical thermodynamic database for hydrated Portland cements and alkali-activated materials

B Lothenbach, DA Kulik, T Matschei, M Balonis… - Cement and Concrete …, 2019 - Elsevier
Thermodynamic modelling can reliably predict hydrated cement phase assemblages and
chemical compositions, including their interactions with prevailing service environments …

Exploring the potential of nonclassical crystallization pathways to advance cementitious materials

C Ruiz-Agudo, H Cölfen - Chemical Reviews, 2024 - ACS Publications
Understanding the crystallization of cement-binding phases, from basic units to macroscopic
structures, can enhance cement performance, reduce clinker use, and lower CO2 emissions …

Application of thermodynamic modelling to hydrated cements

B Lothenbach, M Zajac - Cement and Concrete Research, 2019 - Elsevier
Thermodynamic modelling is essential to understand the effect of binder composition on
hydrate assemblage in modern Portland composite cements and its effect on durability …

Properties of magnesium silicate hydrates (MSH)

D Nied, K Enemark-Rasmussen, E L'Hopital… - Cement and Concrete …, 2016 - Elsevier
Investigations of synthetic magnesium silicate hydrate (MSH) samples have shown that MSH
aged for 1 year can exhibit variable compositions with molar Mg/Si ratios in the range 0.7≤ …

The acceleration mechanism of nano-CSH particles on OPC hydration

F Wang, X Kong, L Jiang, D Wang - Construction and Building Materials, 2020 - Elsevier
In recent decades, a novel concept of accelerating hydration process of cement has been
proposed by adding external nuclei into a hydrating cement system, which is called seeding …

Characterization of magnesium silicate hydrate (MSH)

E Bernard, B Lothenbach, C Chlique… - Cement and concrete …, 2019 - Elsevier
In this study, the structure of synthetic magnesium silicate hydrated phases (MSH) and the
distribution of water as a function of the Mg/Si ratio were investigated. Different analytical …

Effect of magnesium on calcium silicate hydrate (CSH)

E Bernard, B Lothenbach, F Le Goff, I Pochard… - Cement and Concrete …, 2017 - Elsevier
The addition of MgCl 2 to synthetic calcium silicate hydrate (CSH) with Ca/Si= 0.8 lowers the
pH values below 10. Experimental observations and thermodynamic calculations show the …

Use of silica fume and natural volcanic ash as a replacement to Portland cement: Micro and pore structural investigation using NMR, XRD, FTIR and X-ray …

K Kupwade-Patil, SD Palkovic, A Bumajdad… - … and Building Materials, 2018 - Elsevier
This work investigates the effectiveness of the use of volcanic ash along with silica fume as a
partial replacement for Portland cement. Multiple mix combinations of volcanic ash, silica …