Using in-situ laboratory and synchrotron-based x-ray diffraction for lithium-ion batteries characterization: A review on recent developments

AV Llewellyn, A Matruglio, DJL Brett, R Jervis… - Condensed …, 2020 - mdpi.com
Renewable technologies, and in particular the electric vehicle revolution, have generated
tremendous pressure for the improvement of lithium ion battery performance. To meet the …

A practical guide for using electrochemical dilatometry as operando tool in battery and supercapacitor research

I Escher, M Hahn, G A. Ferrero… - Energy …, 2022 - Wiley Online Library
Lithium‐ion batteries and related battery concepts show an expansion and shrinkage
(“breathing”) of the electrodes during cell cycling. The dimensional changes of an individual …

A dilatometric study of graphite electrodes during cycling with X-ray computed tomography

H Michael, F Iacoviello, TMM Heenan… - Journal of The …, 2021 - iopscience.iop.org
Graphite is the most commonly used anode material in commercial lithium-ion batteries
(LiBs). Understanding the mechanisms driving the dimensional changes of graphite can …

Characterizing and mitigating chemomechanical degradation in high-energy lithium-ion battery cathode materials

NS Luu, KY Park, MC Hersam - Accounts of Materials Research, 2022 - ACS Publications
Conspectus Lithium-ion batteries (LIBs) are nearly ubiquitous energy storage solutions,
powering devices ranging from consumer electronics to electric vehicles. To advance these …

Understanding Li plating and strip** behavior in zero-excess Li metal batteries using operando dilatometry

O Lohrberg, S Maletti, C Heubner… - Journal of The …, 2022 - iopscience.iop.org
Zero-excess Li metal batteries (ZELMB), in which the Li-metal anode is plated in situ on the
anode current collector during initial charging, have received considerable attention in …

Understanding anion-redox reactions in cathode materials of lithium-ion batteries through in situ characterization techniques: a review

YY Hwang, JH Han, SH Park, JE Jung, NK Lee… - …, 2022 - iopscience.iop.org
As the demand for rechargeable lithium-ion batteries (LIBs) with higher energy density
increases, the interest in lithium-rich oxide (LRO) with extraordinarily high capacities is …

Developments in dilatometry for characterisation of electrochemical devices

H Michael, R Jervis, DJL Brett… - Batteries & …, 2021 - Wiley Online Library
Since the 1970s, electrochemical dilatometry (ECD) has been used to investigate the
dilation of layered host materials due to the intercalation of guest ions, atoms or molecules …

In situ (operando) electrochemical dilatometry as a method to distinguish charge storage mechanisms and metal plating processes for sodium and lithium ions in hard …

I Escher, G A. Ferrero, M Goktas… - Advanced Materials …, 2022 - Wiley Online Library
In situ (operando) electrochemical dilatometry (ECD) provides information on the
expansion/shrinkage of an electrode during cell cycling. It is shown that the ECD signal can …

Li-rich layered oxides: structure and do** strategies to enable Co-poor/Co-free cathodes for Li-ion batteries

L Silvestri, A Celeste, M Tuccillo, S Brutti - Crystals, 2023 - mdpi.com
Lithium-rich layered oxides (LRLO) are a wide class of innovative active materials used in
positive electrodes in lithium-ion (LIB) and lithium–metal secondary batteries (LMB). LRLOs …

Irreversible dilation of graphite composite anodes influenced by vinylene carbonate

S Ivanov, D Sauerteig, A Dimitrova, S Krischok… - Journal of Power …, 2020 - Elsevier
The volumetric expansion of graphite composite electrodes for Li ion battery is investigated
by electrochemical dilatometry in electrolytes with different concentration of vinylene …