Organoboron compounds possess widespread applications in organic synthesis as well as
pharmaceutical science and materials science. With the rapid development of organic …

A new strategy for the direct cleavage of the C (sp3)–OH bond has been developed via
activation of free alcohols with neutral diphenyl boryl radical generated from sodium …

While the development of weakly coordinating anions (WCAs) received much attention, the
progress on weakly coordinating and inert solvents almost stagnated. Here we study the …

With the development of organoboron chemistry, boron-centered radicals have become
increasingly attractive. However, their synthetic applications remain limited in that they have …

Group 1 elements exhibit the lowest electronegativity values in the Periodic Table. The
chemical reduction of Group 1 metal cations M+ to M (0) is extremely challenging. Common …

Herein we reported the electrochemical hydroboration of alkynes by using B2Pin2 as the
boron source. This unprecedented reaction manifold was applied to a broad range of …

Readily prepared tetraarylborates undergo selective (cross)‐coupling through oxidation with
Bobbitt's salt to give symmetric and unsymmetric biaryls. The organic oxoammonium salt can …

We report herein versatile, transition metal-free and additive-free (hetero) aryl–aryl coupling
reactions promoted by the oxidative electrocoupling of unsymmetrical tetra (hetero) …

In this study, we present an inexpensive, stable, and easily available boryl radical source
(BPh4Na) employed in a Halogen Atom Transfer (XAT) methodology. This mild and …

Tetraphenylborate (BPh4−) has been widely employed in the field of electrolytes and
displayed better ionic conductivities in polymer solid-state Li+ conductors. However, the …