Medium and high oxidation state metal/non-metal fluoride and oxide–fluoride complexes with neutral donor ligands
SL Benjamin, W Levason, G Reid - Chemical Society Reviews, 2013 - pubs.rsc.org
While most high and medium oxidation state (OS≥ 3) metal and non-metal fluorides and
oxide fluorides are strong Lewis acids, exploration of their coordination chemistry with …
oxide fluorides are strong Lewis acids, exploration of their coordination chemistry with …
Coordination complexes and applications of transition metal sulfide and selenide halides
VK Greenacre, W Levason, G Reid, DE Smith - Coordination Chemistry …, 2020 - Elsevier
Metal chalcogenide halides are less studied analogues of metal oxide halides, where the
oxido-group is replaced by heavier Group 16 elements, specifically sulfur, selenium or …
oxido-group is replaced by heavier Group 16 elements, specifically sulfur, selenium or …
Non-precious metal carbamates as catalysts for the aziridine/CO 2 coupling reaction under mild conditions
G Bresciani, S Zacchini, F Marchetti… - Dalton Transactions, 2021 - pubs.rsc.org
The catalytic potential of a large series of easily available metal carbamates (based on
thirteen different non-precious metal elements) was explored for the first time in the coupling …
thirteen different non-precious metal elements) was explored for the first time in the coupling …
Interaction of niobium and tantalum pentahalides with O-donors: coordination chemistry and activation reactions
F Marchetti, G Pampaloni - Chemical Communications, 2012 - pubs.rsc.org
The chemistry of niobium and tantalum pentahalides, MX5, with oxygen compounds is
reviewed herein. The polynuclear structure of MX5 is readily broken by addition of oxygen …
reviewed herein. The polynuclear structure of MX5 is readily broken by addition of oxygen …
Highly selective chemical vapor deposition of tin diselenide thin films onto patterned substrates via single source diselenoether precursors
The distorted octahedral complexes [SnCl4 {n BuSe (CH2) n Se n Bu}](n= 2 or 3),(1) and (2),
obtained from reaction of SnCl4 with the neutral bidentate ligands and characterized by …
obtained from reaction of SnCl4 with the neutral bidentate ligands and characterized by …
Niobium (v) and tantalum (v) halide chalcogenoether complexes–towards single source CVD precursors for ME 2 thin films
A series of pentavalent niobium and tantalum halide complexes with thio-, seleno-and
telluro-ether ligands,[MCl5 (EnBu2)](M= Nb, Ta; E= S, Se, Te),[TaX5 (TeMe2)](X= Cl, Br, F) …
telluro-ether ligands,[MCl5 (EnBu2)](M= Nb, Ta; E= S, Se, Te),[TaX5 (TeMe2)](X= Cl, Br, F) …
Donor‐Stabilised [SbF4]+: SbF5 as a Fluoride‐Ion Donor
F O'Donnell, D Turnbull, SD Wetmore… - … –A European Journal, 2021 - Wiley Online Library
Antimony pentafluoride is a strong Lewis acid and fluoride‐ion acceptor that has not
previously demonstrated any discreet fluoride‐ion donor properties. The first donor …
previously demonstrated any discreet fluoride‐ion donor properties. The first donor …
Fluoride-Ion Donor Properties of AsF5
F O'Donnell, SD Wetmore, M Gerken - Inorganic Chemistry, 2024 - ACS Publications
Arsenic pentafluoride undergoes ligand-induced autoionization in the presence of 1, 10-
phenanthroline (phen) in a SO2ClF solution to form the donor-stabilized [AsF4 (phen)][AsF6] …
phenanthroline (phen) in a SO2ClF solution to form the donor-stabilized [AsF4 (phen)][AsF6] …
Coordination complexes of niobium and tantalum pentahalides with a bulky NHC ligand
The 1: 1 molar reactions of niobium and tantalum pentahalides with the monodentate NHC
ligand 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene (Ipr), in toluene (or benzene) at …
ligand 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene (Ipr), in toluene (or benzene) at …
Soft diphosphine and diarsine complexes of niobium (v) and tantalum (v) fluorides: synthesis, properties, structures and comparisons with the corresponding chlorides
The reactions of the soft diphosphines o-C6H4 (PMe2) 2, Me2P (CH2) 2PMe2, Et2P (CH2)
2PEt2 or o-C6H4 (PPh2) 2 with NbF5 or TaF5 in anhydrous MeCN solution produce [MF4 …
2PEt2 or o-C6H4 (PPh2) 2 with NbF5 or TaF5 in anhydrous MeCN solution produce [MF4 …