Designed to degrade: tailoring polyesters for circularity

CV Aarsen, A Liguori, R Mattsson… - Chemical …, 2024 - ACS Publications
A powerful toolbox is needed to turn the linear plastic economy into circular. Development of
materials designed for mechanical recycling, chemical recycling, and/or biodegradation in …

Dynamic covalent adhesives and their applications: Current progress and future perspectives

Z Liu, Y Tang, Y Chen, Z Lu, Z Rui - Chemical Engineering Journal, 2024 - Elsevier
Thanks to the lightness and suitability for dissimilar material joining, adhesives are
increasingly used to replace welding and bolted connections, but disassembly challenge …

Reconstruction of cellulose intermolecular interactions from hydrogen bonds to dynamic covalent networks enables a thermo-processable cellulosic plastic with …

Z Su, L Yu, L Cui, G Zhou, X Zhang, X Qiu, C Chen… - ACS …, 2023 - ACS Publications
Its excellent renewability and biodegradability make cellulose an attractive resource to
prepare fossil-based plastic alternatives. However, cellulose itself exhibits strong …

High-performance recyclable and malleable epoxy resin with vanillin-based hyperbranched epoxy resin containing dual dynamic bonds

Y Hao, L Zhong, T Li, J Zhang… - … Sustainable Chemistry & …, 2023 - ACS Publications
Dynamic covalent polymer networks represent new opportunities in the design of
sustainable epoxy resins due to their excellent malleability and reprocessability; however …

Design of tough, strong and recyclable plant protein-based adhesive via dynamic covalent crosslinking chemistry

Y Zhou, G Zeng, F Zhang, K Li, X Li, J Luo, J Li… - Chemical Engineering …, 2023 - Elsevier
Conventional covalent crosslinked protein adhesives are brittle and cannot be reprocessed
effectively, which restricts their practical application and limits the recyclability of wood …

High-strength and multi-recyclable epoxy vitrimer containing dual-dynamic covalent bonds based on the disulfide and imine bond metathesis

C Luo, W Wang, W Yang, X Liu, J Lin… - ACS Sustainable …, 2023 - ACS Publications
Epoxy (EP) vitrimers are currently regarded as ideal substitutes for traditional thermosetting
resins, as this class of materials combines the advantages of thermoplastic and thermoset …

High-strength, self-reinforcing and recyclable multifunctional lignin-based polyurethanes based on multi-level dynamic cross-linking

Z Huang, H Wang, J Du, X Liu, G Pan, X Yin… - Chemical Engineering …, 2023 - Elsevier
The preparation of lignin-based polyurethanes with excellent mechanical properties and
recyclability remains extremely challenging because of the poor compatibility of lignin and …

Lignin-Based Covalent Adaptable Network Polymers─ When Bio-Based Thermosets Meet Recyclable by Design

DB Tiz, FA Vicente, A Kroflič… - … Sustainable Chemistry & …, 2023 - ACS Publications
Covalent adaptable networks (CANs) play an important role in polymer chemistry, as they
provide an innovative link between thermoplastics and thermosets. The breakthrough idea …

[HTML][HTML] Recyclable flame retardant phosphonated epoxy based thermosets enabled via a reactive approach

WW Klingler, V Rougier, Z Huang, D Parida… - Chemical Engineering …, 2023 - Elsevier
The development of reusable fire-safe polymers with a prolonged lifetime heralds the switch
for a transition towards circular economy. In this framework, we report a novel phosphonated …

Improving the comprehensive properties of chitosan-based thermal insulation aerogels by introducing a biobased epoxy thermoset to form an anisotropic honeycomb …

C Zhang, S Song, Q Cao, J Li, Q Liu, S Zhang… - International Journal of …, 2023 - Elsevier
Naturally-derived aerogels have attracted considerable attention owing to their good
biocompatibility, biodegradability and sustainability, but their weak mechanical properties …