The purpose of this review is to provide an overview of uranium speciation using vibrational
spectroscopy methods including Raman and IR. Uranium is a naturally occurring …

Over the past four decades, the number of inorganic oxide and oxy-salt phases containing
stoichiometric quantities of hexavalent uranium has increased exponentially from a few …

This study identifies how the amidoximate anion, AO, interacts with the uranyl cation,
UO22+. Density functional theory calculations have been used to evaluate possible binding …

Uranium has varying degrees of oxidation (+ 4 and+ 6) and is responsive to changes in the
redox potential of the environment. It is deposited at the reduction barrier with the …

The structures and vibrational frequencies of UO2 (H2O) 42+ and UO2 (H2O) 52+ have
been calculated using density functional theory and are in reasonable agreement with …

The ability to predict the equilibrium constants for the formation of 1: 1 uranyl/ligand
complexes (log K 1 values) provides the essential foundation for the rational design of …

The capture of uranyl, UO22+, by a recently engineered protein (Zhou et al. Nat. Chem.
2014, 6, 236) with high selectivity and femtomolar sensitivity has been examined by a …

In order to elucidate the uranium solution chemistry at the high HNO3 concentrations
typically employed for the reprocessing of spent nuclear fuels, speciation and complex …

A mixing of metal-loaded acid mine drainage with shallow groundwater or surface waters
usually initiates oxidation and/or hydrolysis of dissolved metals such as iron (Fe) and …

Comprehensive computational modeling of coordination structures, thermodynamic
stabilities, and luminescence spectra of uranyl-glycine-water complexes [UO2 (Gly) n aq m] …