Condensed‐Phase Quantum Chemistry

PJ Robinson, A Rettig, HQ Dinh… - Wiley Interdisciplinary …, 2025 - Wiley Online Library
Molecular quantum chemistry has seen enormous progress in the last few decades thanks
to more advanced and sophisticated numerical techniques and computing power. Following …

A general framework for active space embedding methods with applications in quantum computing

S Battaglia, M Rossmannek, VV Rybkin… - npj Computational …, 2024 - nature.com
We developed a general framework for hybrid quantum-classical computing of molecular
and periodic embedding approaches based on an orbital space separation of the fragment …

Multi-GPU RI-HF Energies and Analytic Gradients─ Toward High-Throughput Ab Initio Molecular Dynamics

R Stocks, E Palethorpe, GMJ Barca - Journal of Chemical Theory …, 2024 - ACS Publications
This article presents an optimized algorithm and implementation for calculating resolution-of-
the-identity Hartree–Fock (RI-HF) energies and analytic gradients using multiple graphics …

The Staggered Mesh Method: Accurate Exact Exchange Toward the Thermodynamic Limit for Solids

SJ Quiton, H Wu, X **ng, L Lin… - Journal of Chemical …, 2024 - ACS Publications
In periodic systems, the Hartree–Fock (HF) exchange energy exhibits the slowest
convergence of all HF energy components as the system size approaches the …

The role of the exact Hartree–Fock exchange in the investigation of defects in crystalline systems

A Platonenko, F Gentile, KE El-Kelany… - Physical Chemistry …, 2024 - pubs.rsc.org
The role of the exact Hartree–Fock (HF) exchange in determining the band gap and other
properties of defects in crystalline solids is investigated. Two defects in diamond, VHd1 and …

Efficient All-electron Hybrid Density Functionals for Atomistic Simulations Beyond 10,000 Atoms

S Kokott, F Merz, Y Yao, C Carbogno, M Rossi… - arxiv preprint arxiv …, 2024 - arxiv.org
Hybrid density functional approximations (DFAs) offer compelling accuracy for ab initio
electronic-structure simulations of molecules, nanosystems, and bulk materials, addressing …

Efficient hybrid-functional-based force and stress calculations for periodic systems with thousands of atoms

P Lin, Y Ji, L He, X Ren - arxiv preprint arxiv:2412.11081, 2024 - arxiv.org
We present an efficient linear-scaling algorithm for evaluating the analytical force and stress
contributions derived from the exact-exchange energy, a key component in hybrid functional …