Dynamics of excitons in conjugated molecules and organic semiconductor systems

OP Dimitriev - Chemical Reviews, 2022 - ACS Publications
The exciton, an excited electron–hole pair bound by Coulomb attraction, plays a key role in
photophysics of organic molecules and drives practically important phenomena such as …

Organic optoelectronic materials: mechanisms and applications

O Ostroverkhova - Chemical reviews, 2016 - ACS Publications
Organic (opto) electronic materials have received considerable attention due to their
applications in thin-film-transistors, light-emitting diodes, solar cells, sensors, photorefractive …

Theoretical modeling of singlet fission

D Casanova - Chemical reviews, 2018 - ACS Publications
Singlet fission is a photophysical reaction in which a singlet excited electronic state splits
into two spin-triplet states. Singlet fission was discovered more than 50 years ago, but the …

Harnessing singlet exciton fission to break the Shockley–Queisser limit

A Rao, RH Friend - Nature reviews materials, 2017 - nature.com
Singlet exciton fission is a carrier multiplication process in organic semiconductors that
generates two electron–hole pairs for each photon absorbed. Singlet fission occurs on sub …

Diradicals

M Abe - Chemical Reviews, 2013 - ACS Publications
Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …

Coherent photoexcitation of entangled triplet pair states

J Kim, DC Bain, V Ding, K Majumder, D Windemuller… - Nature …, 2024 - nature.com
The functional properties of organic semiconductors are defined by the interplay between
optically bright and dark states. Organic devices require rapid conversion between these …

Real-time observation of multiexcitonic states in ultrafast singlet fission using coherent 2D electronic spectroscopy

AA Bakulin, SE Morgan, TB Kehoe, MWB Wilson… - Nature …, 2016 - nature.com
Singlet fission is the spin-allowed conversion of a spin-singlet exciton into a pair of spin-
triplet excitons residing on neighbouring molecules. To rationalize this phenomenon, a …

Ultrafast Exciton Dissociation and Long-Lived Charge Separation in a Photovoltaic Pentacene–MoS2 van der Waals Heterojunction

S Bettis Homan, VK Sangwan, I Balla, H Bergeron… - Nano …, 2017 - ACS Publications
van der Waals heterojunctions between two-dimensional (2D) layered materials and
nanomaterials of different dimensions present unique opportunities for gate-tunable …

Air-and photo-stable luminescent carbodicarbene-azaboraacenium ions

CL Deng, AD Obi, BYE Tra, SK Sarkar, DA Dickie… - Nature Chemistry, 2024 - nature.com
Substitution of a C= C bond by an isoelectronic B–N bond is a well-established strategy to
alter the electronic structure and stability of acenes. BN-substituted acenes that possess …

The entangled triplet pair state in acene and heteroacene materials

CK Yong, AJ Musser, SL Bayliss, S Lukman… - Nature …, 2017 - nature.com
Entanglement of states is one of the most surprising and counter-intuitive consequences of
quantum mechanics, with potent applications in cryptography and computing. In organic …