Negative thermal expansion in framework structure materials
Negative thermal expansion (NTE) is a counterintuitive physical phenomenon that the unit
cell volume of material usually contracts instead of expands upon heating. With two …
cell volume of material usually contracts instead of expands upon heating. With two …
Thermally boosted upconversion and downshifting luminescence in Sc2(MoO4)3:Yb/Er with two-dimensional negative thermal expansion
J Liao, M Wang, F Lin, Z Han, B Fu, D Tu… - Nature …, 2022 - nature.com
Abstract Rare earth (RE3+)-doped phosphors generally suffer from thermal quenching, in
which their photoluminescence (PL) intensities decrease at high temperatures. Herein, we …
which their photoluminescence (PL) intensities decrease at high temperatures. Herein, we …
Thermal Expansion Behavior in the A2M3O12 Family of Materials
H Liu, W Sun, Z Zhang, LN Lovings, C Lind - Solids, 2021 - mdpi.com
Over the past several decades, research on anomalous thermal expansion materials has
been rapidly growing, and increasing numbers of compounds exhibiting negative thermal …
been rapidly growing, and increasing numbers of compounds exhibiting negative thermal …
The enhanced negative thermal expansion in less-oxygen-vacancies copper pyrophosphate
LL **e, TF Shi, JC Lin, XK Zhang, XK Zhong… - Journal of Materials …, 2023 - Elsevier
For oxides, controlling the concentration of oxygen vacancy is a useful way to optimize their
functional properties. However, when it comes to the field of negative thermal expansion …
functional properties. However, when it comes to the field of negative thermal expansion …
Zero Thermal Expansion in ZrMgMo3O12: NMR Crystallography Reveals Origins of Thermoelastic Properties
The coefficient of thermal expansion of ZrMgMo3O12 has been measured and was found to
be extremely close to zero over a wide temperature range including room temperature (α …
be extremely close to zero over a wide temperature range including room temperature (α …
Uniaxial Negative Thermal Expansion in γ-LiBO2 with a Closed-Framework Diamond-Like Structure
Z Liang, H Zhou, Y Li, MS Molokeev… - Chemistry of …, 2024 - ACS Publications
Negative-thermal-expansion (NTE) materials violate the common knowledge of “thermal
expansion and cold contraction” in solids and embrace various physical mechanisms. In …
expansion and cold contraction” in solids and embrace various physical mechanisms. In …
Negative and Near-Zero Thermal Expansion in A 2 M 3O12 and Related Ceramic Families: A Review
This review presents the history of materials in the A 2 M 3O12 and related ceramic families,
including their unusual thermal expansion and the present understanding of its mechanism …
including their unusual thermal expansion and the present understanding of its mechanism …
Correlation between AO6 Polyhedral Distortion and Negative Thermal Expansion in Orthorhombic Y2Mo3O12 and Related Materials
The Pbcn orthorhombic phase of Y2Mo3O12 has been examined through high-resolution X-
ray powder diffraction (10− 450 K), heat capacity determination (2− 390 K), and differential …
ray powder diffraction (10− 450 K), heat capacity determination (2− 390 K), and differential …
A linear calibrated high temperature sensor based on up-conversion fluorescence of Y2Mo3O12: Er3+, Yb3+ enhanced by negative thermal expansion
Y Yang, L Lin, P Lu, Z Feng, Z Li, J Cai, Z Mei… - Journal of …, 2021 - Elsevier
The temperature sensing properties of the Y 2 Mo 3 O 12: Er 3+, Yb 3+ phosphor are
analyzed by using fluorescence intensity ratios (FIRs) of up-conversion (UC) emissions of Er …
analyzed by using fluorescence intensity ratios (FIRs) of up-conversion (UC) emissions of Er …
Structures, Phase Transition, and Crystal Water of Fe2–xYxMo3O12
ZY Li, WB Song, EJ Liang - The Journal of Physical Chemistry C, 2011 - ACS Publications
Materials with the formula Fe2–x Y x Mo3O12 (x= 0.2, 0.4, 0.5, 0.6, 0.8, 1.0, 1.2, 1.4, 1.6, and
1.8) have been synthesized, and their structures, phase transitions, hygroscopicity, and …
1.8) have been synthesized, and their structures, phase transitions, hygroscopicity, and …