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Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes
The generation of polymer brushes by surface-initiated controlled radical polymerization (SI-
CRP) techniques has become a powerful approach to tailor the chemical and physical …
CRP) techniques has become a powerful approach to tailor the chemical and physical …
[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …
Surface-initiated polymer brushes in the biomedical field: applications in membrane science, biosensing, cell culture, regenerative medicine and antibacterial coatings
M Krishnamoorthy, S Hakobyan, M Ramstedt… - Chemical …, 2014 - ACS Publications
Understanding and controlling interfaces has proven to be key to a very wide range of
applications, from optical and electronic materials 1, 2 to energy storage and production, 3 …
applications, from optical and electronic materials 1, 2 to energy storage and production, 3 …
High-affinity detection and capture of heavy metal contaminants using block polymer composite membranes
Adsorptive membranes offer one possible solution to the challenge of removing and
recovering heavy metal ion contaminants and resources from water supplies. However …
recovering heavy metal ion contaminants and resources from water supplies. However …
Weak polyelectrolyte brushes
M Geoghegan - Soft Matter, 2022 - pubs.rsc.org
Weak polyelectrolyte brushes - Soft Matter (RSC Publishing) DOI:10.1039/D2SM00005A Royal
Society of Chemistry View PDF VersionPrevious ArticleNext Article Check for updates Open …
Society of Chemistry View PDF VersionPrevious ArticleNext Article Check for updates Open …
Block polymer membranes functionalized with nanoconfined polyelectrolyte brushes achieve sub-nanometer selectivity
The well-defined nanostructure of membranes manufactured from self-assembled block
polymers enables highly selective separations; however, recent efforts to push the pore size …
polymers enables highly selective separations; however, recent efforts to push the pore size …
Enzyme immobilization in polyelectrolyte brushes: High loading and enhanced activity compared to monolayers
Catalysis by enzymes on surfaces has many applications. However, strategies for efficient
enzyme immobilization with preserved activity are still in need of further development. In this …
enzyme immobilization with preserved activity are still in need of further development. In this …
Hydration state variation of polyzwitterion brushes through interplay with ions
Polyzwitterions have emerged as a new class of antifouling materials alternating poly
(ethylene glycol). The exemplary biopassivation and lubrication behaviors are often …
(ethylene glycol). The exemplary biopassivation and lubrication behaviors are often …
Large changes in protonation of weak polyelectrolyte brushes with salt concentration—Implications for protein immobilization
G Ferrand-Drake del Castillo, RLN Hailes… - The Journal of …, 2020 - ACS Publications
We report for the first time that the protonation behavior of weak polyelectrolyte brushes
depends very strongly on ionic strength. The p K a changes by one pH step per order of …
depends very strongly on ionic strength. The p K a changes by one pH step per order of …
Hysteretic memory in pH-response of water contact angle on poly (acrylic acid) brushes
We investigated the pH-dependent response of flat polyacid brushes of varying length and
dispersity in the extended brush regime. Our model system consisted of poly (acrylic acid) …
dispersity in the extended brush regime. Our model system consisted of poly (acrylic acid) …