Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Solar‐to‐hydrogen energy conversion based on water splitting

J Qi, W Zhang, R Cao - Advanced Energy Materials, 2018 - Wiley Online Library
Artificial photosynthesis provides a blueprint to harvest solar energy to sustain the future
energy demands. Solar‐driven water splitting, converting solar energy into hydrogen …

Earth-abundant hydrogen evolution electrocatalysts

JR McKone, SC Marinescu, BS Brunschwig… - Chemical …, 2014 - pubs.rsc.org
Splitting water to hydrogen and oxygen is a promising approach for storing energy from
intermittent renewables, such as solar power. Efficient, scalable solar-driven electrolysis …

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s−1 for H2 Production

ML Helm, MP Stewart, RM Bullock, MR DuBois… - Science, 2011 - science.org
Reduction of acids to molecular hydrogen as a means of storing energy is catalyzed by
platinum, but its low abundance and high cost are problematic. Precisely controlled delivery …

Molecular systems for light driven hydrogen production

WT Eckenhoff, R Eisenberg - Dalton Transactions, 2012 - pubs.rsc.org
Recent work towards the production of hydrogen via reduction of protons is described. Most
of the systems examined in this perspective use a molecular chromophore for harvesting …

A cobalt–dithiolene complex for the photocatalytic and electrocatalytic reduction of protons

WR McNamara, Z Han, PJ Alperin… - Journal of the …, 2011 - ACS Publications
The complex [Co (bdt) 2]−(where bdt= 1, 2-benzenedithiolate) is an active catalyst for the
visible light driven reduction of protons from water when employed with Ru (bpy) 32+ as the …

Efficient electrocatalytic proton reduction with carbon nanotube-supported metal–organic frameworks

D Micheroni, G Lan, W Lin - Journal of the American Chemical …, 2018 - ACS Publications
Hydrogen production from Earth-abundant catalysts remains an important but difficult
challenge. Here we report the growth of Hf12-porphyrin metal–organic frameworks (MOFs) …

Cooperative catalysis with first‐row late transition metals

JI van der Vlugt - European Journal of Inorganic Chemistry, 2012 - Wiley Online Library
Cooperative catalysis with first‐row transition metals holds much promise for future
developments regarding sustainable, selective transformations, including eg alkenes …

Electrocatalytic and photocatalytic hydrogen production in aqueous solution by a molecular cobalt complex

WM Singh, T Baine, S Kudo, S Tian… - Angewandte …, 2012 - Wiley Online Library
Hydrogen as a source of clean and renewable fuel has attracted great interest because of its
potential to reduce the current dependence on fossil fuels.[1] Reduction of water to H2 …

Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides

RM Bullock, AM Appel, ML Helm - Chemical Communications, 2014 - pubs.rsc.org
Generation of hydrogen by reduction of two protons by two electrons can be catalysed by
molecular electrocatalysts. Determination of the thermodynamic driving force for elimination …