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Design principles for strong and tough hydrogels
Hydrogels are crosslinked polymer networks swollen with water. Owing to their soft and
water-containing nature, hydrogels are promising materials for applications in many fields …
water-containing nature, hydrogels are promising materials for applications in many fields …
Naphthopyran molecular switches and their emergent mechanochemical reactivity
Naphthopyran molecular switches undergo a ring-opening reaction upon external
stimulation to generate intensely colored merocyanine dyes. Their unique modularity and …
stimulation to generate intensely colored merocyanine dyes. Their unique modularity and …
Ultraflexible, cost-effective and scalable polymer-based phase change composites via chemical cross-linking for wearable thermal management
Y **g, Z Zhao, X Cao, Q Sun, Y Yuan, T Li - Nature Communications, 2023 - nature.com
Phase change materials (PCMs) offer great potential for realizing zero-energy thermal
management due to superior thermal storage and stable phase-change temperatures …
management due to superior thermal storage and stable phase-change temperatures …
High strength and toughness polymeric triboelectric materials enabled by dense crystal-domain cross-linking
Lightweight, easily processed, and durable polymeric materials play a crucial role in
wearable sensor devices. However, achieving simultaneously high strength and toughness …
wearable sensor devices. However, achieving simultaneously high strength and toughness …
Sacrificial mechanical bond is as effective as a sacrificial covalent bond in increasing cross-linked polymer toughness
Sacrificial chemical bonds have been used effectively to increase the toughness of
elastomers because such bonds dissociate at forces significantly below the fracture limit of …
elastomers because such bonds dissociate at forces significantly below the fracture limit of …
The tension-activated carbon–carbon bond
Mechanical force drives distinct chemical reactions; yet, its vectoral nature results in
complicated coupling with reaction trajectories. Here, we utilize a physical organic model …
complicated coupling with reaction trajectories. Here, we utilize a physical organic model …
Self-Amplified HF Release and Polymer Deconstruction Cascades Triggered by Mechanical Force
Hydrogen fluoride (HF) is a versatile reagent for material transformation, with applications in
self-immolative polymers, remodeled siloxanes, and degradable polymers. The responsive …
self-immolative polymers, remodeled siloxanes, and degradable polymers. The responsive …
Machine learning-assisted design of advanced polymeric materials
Conspectus Polymeric material research is encountering a new paradigm driven by
machine learning (ML) and big data. The ML-assisted design has proven to be a successful …
machine learning (ML) and big data. The ML-assisted design has proven to be a successful …
Leveraging mechanochemistry for sustainable polymer degradation
Over 8 billion tons of plastic have been produced to date, and a 100% reclamation recycling
strategy is not foreseeable. This review summarizes how the mechanochemistry of polymers …
strategy is not foreseeable. This review summarizes how the mechanochemistry of polymers …
Thermoresponsive helical dendronized poly (phenylacetylene) s: remarkable stabilization of their helicity via photo-dimerization of the dendritic pendants
L Ren, X Lu, W Li, J Yan, AK Whittaker… - Journal of the American …, 2023 - ACS Publications
Dynamic helical polymers can change their helicity according to external stimuli due to the
low helix-inversion barriers, while helicity stabilization for polymers is important for …
low helix-inversion barriers, while helicity stabilization for polymers is important for …