Tunable topological phases in nanographene-based spin-1/2 alternating-exchange Heisenberg chains

C Zhao, G Catarina, JJ Zhang, JCG Henriques… - Nature …, 2024 - nature.com
Unlocking the potential of topological order in many-body spin systems has been a key goal
in quantum materials research. Despite extensive efforts, the quest for a versatile platform …

Conformational tuning of magnetic interactions in coupled nanographenes

G Catarina, E Turco, N Krane, M Bommert… - Nano Letters, 2024 - ACS Publications
Phenalenyl (C13H9) is an open-shell spin-1/2 nanographene. Using scanning tunneling
microscopy (STM) inelastic electron tunneling spectroscopy (IETS), covalently bonded …

Atomically Precise Control of Topological State Hybridization in Conjugated Polymers

A Jiménez-Martín, Z Sosnová, D Soler, B Mallada… - ACS …, 2024 - ACS Publications
Realization of topological quantum states in carbon nanostructures has recently emerged as
a promising platform for hosting highly coherent and controllable quantum dot spin qubits …

Gapless spin excitations in nanographene-based antiferromagnetic spin-1/2 Heisenberg chains

C Zhao, L Yang, JCG Henriques, M Ferri-Cortés… - arxiv preprint arxiv …, 2024 - arxiv.org
Haldane's seminal work established two fundamentally different types of excitation spectra
for antiferromagnetic Heisenberg quantum spin chains: gapped excitations in integer-spin …

Beyond Spin Models in Orbitally Degenerate Open-Shell Nanographenes

J Henriques, D Jacob, A Molina-Sánchez… - Nano Letters, 2024 - ACS Publications
The study of open-shell nanographenes has relied on a paradigm where spins are the only
low-energy degrees of freedom. Here we show that some nanographenes can host low …

Thermal spin-crossover and temperature-dependent zero-field splitting in magnetic nanographene chains

Y Wang, AP Paz, EV Boström, X Zhang, J Li… - arxiv preprint arxiv …, 2024 - arxiv.org
Nanographene-based magnetism at interfaces offers an avenue to designer quantum
materials towards novel phases of matter and atomic-scale applications. Key to spintronics …

Globally aromatic odd-electron π-magnetic macrocycle

F Villalobos, J Berger, A Matěj, R Nieman… - Chem, 2024 - cell.com
Molecular π-magnets based on single organic molecules have attracted increasing attention
for their potential applications in optoelectronics and spintronics. Global aromaticity in …

Unveiling the mysterious hydrocarbon–Clar's goblet

T Jiao, CH Wu, YS Zhang, X Miao, S Wu, SD Jiang… - 2024 - chemrxiv.org
In the classic view, spin pairing occurs between two electrons in a chemical bond where the
bonding interaction compensates for the penalty of electrostatic repulsion. It is a mystery …

General principle behind magnetization-induced second-order topological corner states in the Kane-Mele model

CM Miao, L Liu, YH Wan, QF Sun, YT Zhang - Physical Review B, 2024 - APS
We propose a general principle for realizing second-order topological corner states in the
modified Kane-Mele model with magnetization. It is demonstrated that the sign of the edge …

Insights into quantum tunneling via a phase-space approach

C Chen, S Zhou - Physical Review A, 2024 - APS
Quantum tunneling, as a quintessential quantum phenomenon, has been investigated in
detail both theoretically and experimentally. Still, the physical picture of the tunneling …