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The Cinderella Nuclei
BE Mann - Annual Reports on NMR Spectroscopy, 1991 - Elsevier
Publisher Summary The chapter discusses the cinderella nuclei. The sensitivity of these
nuclei is low. All the nuclei are less sensitive than 13 C, with 187 Os having only 1/877 the …
nuclei is low. All the nuclei are less sensitive than 13 C, with 187 Os having only 1/877 the …
Molybdenum-95 NMR Spectroscopy
J Malito - Annual Reports on NMR Spectroscopy, 1996 - Elsevier
Publisher Summary 95 Mo NMR has become an increasingly useful probe for the
characterization of a wide variety of molybdenum complexes in different situations. This …
characterization of a wide variety of molybdenum complexes in different situations. This …
Water Exchange from the Oxo-Centered Rhodium(III) Trimer [Rh3(μ3-O)(μ-O2CCH3)6(OH2)3]+: A High-Pressure 17O NMR Study
JR Houston, P Yu, WH Casey - Inorganic chemistry, 2005 - ACS Publications
Water exchange from the oxo-centered rhodium (III) trimer,[Rh3 (μ3-O)(μ-O2CCH3) 6 (OH2)
3]+, was investigated using variable-temperature (272.8− 281.6 K) and variable-pressure …
3]+, was investigated using variable-temperature (272.8− 281.6 K) and variable-pressure …
Mechanism of Pyridine−Ligand Exchanges at the Different Labile Sites of 3d Heterometallic and Mixed Valence μ3-oxo Trinuclear Clusters
G Novitchi, F Riblet, R Scopelliti, L Helm… - Inorganic …, 2008 - ACS Publications
The syntheses and single crystal X-ray structural analysis of five novel hetero-and
homometallic μ3-oxo trinuclear cluster with the formula [FeIII2MII (μ3-O)(μ-O2CCH3) 6 (4 …
homometallic μ3-oxo trinuclear cluster with the formula [FeIII2MII (μ3-O)(μ-O2CCH3) 6 (4 …
The tetranuclear ruthenium (IV) aqua ion: evidence in support of its formulation as Hn [Ru4O6 (OH2) 12](4+ n)+(n= 0-4)
A Patel, DT Richens - Inorganic Chemistry, 1991 - ACS Publications
Surprisingly no derivative complexes (replacement of coordinated water ligands) have been
characterized in the hope of shedding light on the nature of the core structure. We, like …
characterized in the hope of shedding light on the nature of the core structure. We, like …
Reduction of the incomplete cuboidal molybdenum (IV) aqua ion [Mo3 (µ3-O)(µ-O) 3 (OH2) 9] 4+ by Eu2+. Characterisation of the trinuclear molybdenum (III) and …
DT Richens, C Guille-Photin - Journal of the Chemical Society, Dalton …, 1990 - pubs.rsc.org
Reduction of 17O-enriched samples of [Mo3 (µ3-O)(µ-O) 3 (OH2) 9] 4+ by Eu2+ in toluene-p-
sulphonic acid (Hpts) solution has allowed an evaluation of the solution molecular structures …
sulphonic acid (Hpts) solution has allowed an evaluation of the solution molecular structures …
The Transition Metals: Groups 3–12
RB Jordan - Principles of Inorganic Chemistry: Basics and …, 2024 - Springer
Many properties of these elements are tabulated in this chapter, followed by descriptions of
each group. These descriptions include the properties of each metal, the natural sources …
each group. These descriptions include the properties of each metal, the natural sources …
STRUCTURE-PROPERTY RELATIONSHIPS IN POLYNUCLEAR µ-O BRIDGED AQUA CLUSTERS: EFFECT OF M-µO BOND COVALENCY
DT Richens - Comments on Inorganic Chemistry, 2005 - Taylor & Francis
The extent of M-µO bond covalency is the dominant factor controlling the M-µO distance, the
terminal water pKa and exchange mechanism within a range of polynuclear oxo-bridged …
terminal water pKa and exchange mechanism within a range of polynuclear oxo-bridged …
Characterisation of a cationic triniobium aqua ion cluster and related studies
S Minhas, DT Richens - Journal of the Chemical Society, Dalton …, 1996 - pubs.rsc.org
A green air-sensitive niobium cation has been characterised in acidic aqueous solutions
following Dowex cation-exchange column chromatography of hydrolysed solutions of …
following Dowex cation-exchange column chromatography of hydrolysed solutions of …
Mixed-valence state of a series of sulfur-bridged triangular trinuclear molybdenum and tungsten clusters [MonW3− nS4 (Hnta) 3] 3−(n= 0–3)
H Takagi, A Ichimura, T Shibahara - Inorganic Chemistry Communications, 1999 - Elsevier
The mixed-valence state of IV, IV, III of a series of triangular clusters having the general
formula [M3S4 (Hnta) 3] 3−, where M= Mo3, Mo2W, MoW2 and W3, and H3nta …
formula [M3S4 (Hnta) 3] 3−, where M= Mo3, Mo2W, MoW2 and W3, and H3nta …