The analytical representation of electronic potential-energy surfaces

GC Schatz - Reviews of Modern Physics, 1989 - APS
This article reviews the commonly used methods for representing electronic potential-energy
surfaces for small molecules and simple chemical reactions in terms of globally defined …

Sulfur chemistry in the atmospheres of warm and hot Jupiters

R Hobbs, PB Rimmer, O Shorttle… - Monthly Notices of the …, 2021 - academic.oup.com
We present and validate a new network of atmospheric thermochemical and photochemical
sulfur reactions. We use a 1D chemical kinetics model to investigate these reactions as part …

Quantitative detection of H 2 S and CS 2 mixed gases based on UV absorption spectrometry

X Zhang, Z Cui, Z Cheng, Y Li, H **ao - RSC advances, 2017 - pubs.rsc.org
H2S and CS2 are the decomposition components of insulating gas SF6. The detection of
these two gases is significant for the online monitoring and fault diagnosis of SF6 electrical …

UV absorption cross-sections of selected sulfur-containing compounds at temperatures up to 500 C

H Grosch, A Fateev, S Clausen - Journal of Quantitative Spectroscopy and …, 2015 - Elsevier
The temperature dependence of the ultraviolet absorption cross-sections of three different
sulfur containing compounds, hydrogen sulfide (H 2 S), carbon disulfide (CS 2) and carbonyl …

Global potential energy surfaces for the lowest 1A′, 3A″, and 1A″ states of HNO

R Guadagnini, GC Schatz, SP Walch - The Journal of chemical physics, 1995 - pubs.aip.org
We present global ab initio potential energy surfaces for the three lowest energy 1 A′, 3 A
″, and 1 A ″surfaces of HNO. These surfaces are the lowest three states of the HNO and …

On the UV photodissociation dynamics of hydrogen iodide

SR Langford, PM Regan, AJ Orr-Ewing, MNR Ashfold - Chemical physics, 1998 - Elsevier
The near ultraviolet photodissociation of hydrogen iodide has been investigated in detail
using the technique of H Rydberg atom photofragment translational spectroscopy …

Supercollisions of fast H-atom with ethylene on an accurate full-dimensional potential energy surface

YL Fu, X Lu, YC Han, B Fu, DH Zhang - The Journal of Chemical …, 2021 - pubs.aip.org
The collisions transferring large portions of energy are often called supercollisions. In the H+
C 2 H 2 reactive system, the rovibrationally cold C 2 H 2 molecule can be activated with …

The infinite‐order sudden approximation for collisions involving molecules in Π electronic states: A new derivation and calculations of rotationally inelastic cross …

GC Corey, MH Alexander - The Journal of chemical physics, 1986 - pubs.aip.org
A new derivation is presented of the infinite‐order sudden (IOS) approximation for
rotationally inelastic collisions of a diatomic molecule in a Π electronic state with a closed …

On the ultraviolet photofragmentation of hydrogen iodide

AB Alekseyev, HP Liebermann, DB Kokh… - The Journal of …, 2000 - pubs.aip.org
Using JCP format Page 1 On the ultraviolet photofragmentation of hydrogen iodide Aleksey B.
Alekseyev,a) Heinz-Peter Liebermann, Daria B. Kokh, and Robert J. Buenker Bergische …

Chemical activation through super energy transfer collisions

JM Smith, M Nikow, J Ma, MJ Wilhelm… - Journal of the …, 2014 - ACS Publications
Can a molecule be efficiently activated with a large amount of energy in a single collision
with a fast atom? If so, this type of collision will greatly affect molecular reactivity and …