Three-and four-membered rings, widespread motifs in nature and medicinal chemistry, have
fascinated chemists ever since their discovery. However, due to energetic considerations …

Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles | Chemical Reviews
ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

The three-component reactions of enaminones, α-diazo esters/ketones, and t-butyl nitrite
(TBN) for the switchable synthesis of isomeric isoxazoles have been realized. The catalysis …

The release of the inherent ring strain of cyclobutane and cyclopropane derivatives allows a
rapid build-up of molecular complexity. This review highlights the state-of-the-art of the ring …

Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition
reactions that allow highly efficient construction of various carbocycles and heterocycles …

A blue light-promoted cross-coupling of two distinct diazo compounds was described. The
reaction produces E-configured trisubstituted alkenes in good yields in the absence of …

A gold (I)‐catalyzed cross‐coupling of diazo compounds to afford tetrasubstituted alkenes
has been developed by taking advantage of a trivial electronic difference between two diazo …

Vinyl diazo compounds are of great interest since they can both serve as carbene
precursors to react with nucleophiles and act as nucleophiles to react with electrophiles via …

An unprecedented gold‐catalyzed ligand‐controlled cross‐coupling of diazo compounds by
sequential selective denitrogenation and cyclization affords N‐substituted pyrazoles in a …

Abstract The first asymmetric [3+ 1]‐cycloaddition was successfully achieved by copper (I)
triflate/double‐sidearmed bisoxazoline complex catalyzed reactions of β‐triisopropylsilyl …