Fluorite-pyrochlore phase transition in nanostructured Ln2Hf2O7 (Ln= La-Lu)

VV Popov, AP Menushenkov, AA Yaroslavtsev… - Journal of Alloys and …, 2016 - Elsevier
Complex oxides of the Ln 2 Hf 2 O 7 (Ln= lanthanide) series undergo a fluorite to pyrochlore
phase transformation. We have studied the whole process of the crystal and local atomic …

Formation and evolution of crystal and local structures in nanostructured Ln2Ti2O7 (Ln= Gd–Dy)

VV Popov, AP Menushenkov, BR Gaynanov… - Journal of Alloys and …, 2018 - Elsevier
Abstract The lanthanide titanates Ln 2 Ti 2 O 7 (Ln= lanthanide) demonstrate a very broad
range of structural, chemical and physical properties. We have studied the whole process of …

Ceramics based on the Sm2O3–Y2O3 and Sm2O3–HfO2 systems at high temperatures: thermodynamics and modeling

VL Stolyarova, VA Vorozhtcov, AL Shilov… - Materials Chemistry and …, 2020 - Elsevier
Ceramics based on the Sm 2 O 3–Y 2 O 3 and Sm 2 O 3–HfO 2 systems is promising for
development of advanced refractory materials including casting molds for gas turbine …

Comparative analysis of long-and short-range structures features in titanates Ln2Ti2O7 and zirconates Ln2Zr2O7 (Ln= Gd, Tb, Dy) upon the crystallization process

VV Popov, AP Menushenkov, AA Ivanov… - Journal of Physics and …, 2019 - Elsevier
We report a comparative study of Ln 2 M 2 O 7 (Ln= Gd, Tb, Dy; M= Ti, Zr) synthesized by
combination of the sol-gel and coprecipitation methods followed by calcination at elevated …

Thermodynamic Functions of Dy2O3⋅2HfO2 Solid Solution and the Schottky Anomaly

AV Guskov, PG Gagarin, VN Guskov, AV Tyurin… - Russian Journal of …, 2022 - Springer
Results are presented from measuring the molar heat capacity of the Dy2O3‧ 2HfO2 solid
solution in the range of 2.5–346 K. The entropy, enthalpy increment, and reduced Gibbs …

Features of formation and evolution of crystal and local structures in nanocrystalline Ln2Zr2O7 (Ln= La-Tb)

VV Popov, AP Menushenkov… - Journal of Physics …, 2017 - iopscience.iop.org
The formation of nanocrystal powders of Ln 2 Zr 2 O 7 (Ln= La-Tb) compounds upon
calcinations up to 1500 C has been investigated by using of X-ray absorption fine structure …

Stabilization of the fluorite phase in the ZrO2–Y2O3 system

VV Popov, AA Yastrebtsev, IS Smirnov… - Russian Metallurgy …, 2016 - Springer
The calculated and experimental vertical ZrO 2–Y 2 O 3 sections of the Zr–Y–O system are
compared to find the region of a stable fluorite structure of yttrium-stabilized zirconia (YSZ). X …

Regularities of formation of complex oxides with the fluorite structure in the ZrO2–Y2O3 system

VV Popov, AP Menushenkov, AA Yastrebtsev… - Russian Journal of …, 2017 - Springer
The crystal and local structures of the complex oxides (1–x) ZrO 2∙ x Y 2 O 3 (YSZ)(x= 0.08–
0.40) prepared by precipitation from solutions of metal salts followed by heat treatment in air …

The effect of synthesis conditions on the structure of compounds formed in the Dy2O3–TiO2 system

VV Popov, AP Menushenkov, AA Yastrebtsev… - Russian Journal of …, 2016 - Springer
Crystallization and phase transition processes taking place in the Dy 2 O 3–TiO 2 system
during the isothermal annealing of the precursors synthesized by co-precipitation were …

Rearrangement in the local, electronic and crystal structure of europium titanates under reduction and oxidation

VV Popov, AP Menushenkov, AY Molokova… - Journal of Alloys and …, 2020 - Elsevier
We studied powder samples of europium titanates Eu 1− x 2+ Eu x 3+ TiO 3+ x/2 prepared
by sol-gel and coprecipitation methods with subsequent thermal treatment of precursors at …