This review summarizes the advancements in rhodium-catalyzed asymmetric C–H
functionalization reactions during the last two decades. Parallel to the rapidly developed …

Organic compounds labeled with hydrogen isotopes play a crucial role in numerous areas,
from materials science to medicinal chemistry. Indeed, while the replacement of hydrogen by …

Silicon-stereogenic chiral organosilanes have found increasing applications in synthetic
chemistry, medicinal chemistry, and materials science. In this context, various asymmetric …

Direct C–H functionalization has recently emerged as one of the most efficient strategies to
access structurally complex molecules from readily accessible feedstocks in an atom-and …

Silicon-stereogenic organosilanes have attracted heightened attention in various scientific
communities including synthetic chemistry, material chemistry, and medicinal chemistry …

Silacycles have exhibited significant potential for application in the fields of medicinal
chemistry, agrochemistry, and materials science. Accordingly, the development of effective …

N-heterocyclic carbene-catalyzed enantioselective kinetic resolutions, dynamic kinetic
resolutions, and desymmetrization reactions are systematically reviewed. The content is …

Transition-metal-catalyzed intermolecular annulation of silicon reagents with organic
molecules is still underdeveloped due to the scarcity of silicon reagent types and their …

Despite impressive advances in the construction of enantioenriched silacarbocycles
featuring silicon‐stereogenic centers via a selection of well‐defined sila‐synthons, the …

One of the most straightforward approaches to access chiral silanes is catalytic
enantioselective hydrosilylation. Although significant advances have been achieved in …