Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis

D Leybo, UJ Etim, M Monai, SR Bare… - Chemical Society …, 2024 - pubs.rsc.org
Supported metal catalysts are essential to a plethora of processes in the chemical industry.
The overall performance of these catalysts depends strongly on the interaction of adsorbates …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Defects Tune the Strong Metal–Support Interactions in Copper Supported on Defected Titanium Dioxide Catalysts for CO2 Reduction

R Belgamwar, R Verma, T Das… - Journal of the …, 2023 - ACS Publications
A highly active and stable Cu-based catalyst for CO2 to CO conversion was demonstrated
by creating a strong metal–support interaction (SMSI) between Cu active sites and the TiO2 …

Tracking the formation, fate and consequence for catalytic activity of Pt single sites on CeO2

F Maurer, J Jelic, J Wang, A Gänzler, P Dolcet, C Wöll… - Nature Catalysis, 2020 - nature.com
Platinum single sites are highly attractive due to their high atom economy and can be
generated on CeO2 by an oxidative high-temperature treatment. However, their location and …

Structure Sensitivity of Au‐TiO2 Strong Metal–Support Interactions

Y Zhang, JX Liu, K Qian, A Jia, D Li… - Angewandte Chemie …, 2021 - Wiley Online Library
Strong metal–support interactions (SMSI) is an important concept in heterogeneous
catalysis. Herein, we demonstrate that the Au‐TiO2 SMSI of Au/TiO2 catalysts sensitively …

Oxygen vacancies‐rich metal oxide for electrocatalytic nitrogen cycle

X Wei, C Chen, XZ Fu, S Wang - Advanced Energy Materials, 2024 - Wiley Online Library
The development of industry and agriculture has been accompanied by an artificially
imbalanced nitrogen cycle, which threatens human health and ecological environments …

Low-Temperature CO2 Methanation over CeO2-Supported Ru Single Atoms, Nanoclusters, and Nanoparticles Competitively Tuned by Strong Metal–Support …

Y Guo, S Mei, K Yuan, DJ Wang, HC Liu, CH Yan… - ACS …, 2018 - ACS Publications
CO2 hydrogenation for the acquisition of value-added chemicals is an economical means to
deal with the CO2-relevant environmental problems, among which CO2 reduction to CH4 is …

Reversing the charge transfer between platinum and sulfur-doped carbon support for electrocatalytic hydrogen evolution

QQ Yan, DX Wu, SQ Chu, ZQ Chen, Y Lin… - Nature …, 2019 - nature.com
Metal–support interaction is of great significance for catalysis as it can induce charge
transfer between metal and support, tame electronic structure of supported metals, impact …

Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts

JC Matsubu, S Zhang, L DeRita, NS Marinkovic… - Nature …, 2017 - nature.com
The optimization of supported metal catalysts predominantly focuses on engineering the
metal site, for which physical insights based on extensive theoretical and experimental …