The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …

For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …

Semiconductor-based photoredox catalysis brings an innovative strategy for sustainable
organic transformation (eg, C–C/C–X bond formation), via radical coupling under mild …

Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

Azetidines are prominent structural scaffolds in bioactive molecules, medicinal chemistry,
and ligand design for transition metals. However, state-of-the-art methods cannot be applied …

Conspectus Nitrogen-centered radicals (NCRs) are a versatile class of highly reactive
species that have a longer history than the classical carbon-based radicals in synthetic …

Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

Monitoring reactive intermediates can provide vital information in the study of synthetic
reaction mechanisms, enabling the design of new catalysts and methods. Many synthetic …

Over the past decade, photoredox catalysis has risen to the forefront of synthetic organic
chemistry as an indispensable tool for selective small-molecule activation and chemical …

Radicals are an important class of versatile and highly reactive species. Compared with the
wide applications of various C-centred radicals, however, the N-radical species including N …