Two-dimensional polymers and polymerizations
Synthetic chemists have developed robust methods to synthesize discrete molecules, linear
and branched polymers, and disordered cross-linked networks. However, two-dimensional …
and branched polymers, and disordered cross-linked networks. However, two-dimensional …
Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis
S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …
creating new organic materials. A large number of chemical reactions have been …
Structurally constrained boron-, nitrogen-, silicon-, and phosphorus-centered polycyclic π-conjugated systems
M Hirai, N Tanaka, M Sakai, S Yamaguchi - Chemical reviews, 2019 - ACS Publications
Incorporation of main group elements into the π-conjugated frameworks is a sophisticated
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …
Synthesis of mesoscale ordered two-dimensional π-conjugated polymers with semiconducting properties
Two-dimensional materials with high charge carrier mobility and tunable band gaps have
attracted intense research effort for their potential use in nanoelectronics. Two-dimensional …
attracted intense research effort for their potential use in nanoelectronics. Two-dimensional …
Tailoring dense, orientation–tunable, and interleavedly structured carbon‐based heat dissipation plates
The controllability of the microstructure of a compressed hierarchical building block is
essential for optimizing a variety of performance parameters, such as thermal management …
essential for optimizing a variety of performance parameters, such as thermal management …
Topological two-dimensional polymers
There are more than 200 two-dimensional (2D) networks with different topologies. The
structural topology of a 2D network defines its electronic structure. Including the electronic …
structural topology of a 2D network defines its electronic structure. Including the electronic …
2D materials and heterostructures at extreme pressure
Abstract 2D materials possess wide‐tuning properties ranging from semiconducting and
metallization to superconducting, etc., which are determined by their structure, empowering …
metallization to superconducting, etc., which are determined by their structure, empowering …
Surface-assisted Ullmann coupling
M Lackinger - Chemical Communications, 2017 - pubs.rsc.org
Surface-assisted Ullmann coupling is the workhorse of on-surfaces synthesis. Among the
various couplings that were successfully transferred from solution to solid surfaces, Ullmann …
various couplings that were successfully transferred from solution to solid surfaces, Ullmann …
2D Honeycomb‐Kagome Polymer Tandem as Effective Metal‐Free Photocatalysts for Water Splitting
On the basis of first‐principles calculations, the potential of applying 2D honeycomb‐
kagome polymers made of heteroatom‐centered triangulene derivatives to photocatalyze …
kagome polymers made of heteroatom‐centered triangulene derivatives to photocatalyze …
Synthesis, hole do**, and electrical properties of a semiconducting azatriangulene-based covalent organic framework
Two-dimensional covalent organic frameworks (2D COFs) containing heterotriangulenes
have been theoretically identified as semiconductors with tunable, Dirac-cone-like band …
have been theoretically identified as semiconductors with tunable, Dirac-cone-like band …