An overview of computational methods for chemical equilibrium and kinetic calculations for geochemical and reactive transport modeling

AMM Leal, DA Kulik, WR Smith… - Pure and Applied …, 2017 - degruyter.com
We present an overview of novel numerical methods for chemical equilibrium and kinetic
calculations for complex non-ideal multiphase systems. The methods we present for …

Implementing an equation of state without derivatives: teqp

IH Bell, UK Deiters, AMM Leal - Industrial & Engineering …, 2022 - ACS Publications
This work uses advanced numerical techniques (complex differentiation and automatic
differentiation) to efficiently and accurately compute all the required thermodynamic …

Computational methods for reactive transport modeling: A Gibbs energy minimization approach for multiphase equilibrium calculations

AMM Leal, DA Kulik, G Kosakowski - Advances in Water Resources, 2016 - Elsevier
We present a numerical method for multiphase chemical equilibrium calculations based on
a Gibbs energy minimization approach. The method can accurately and efficiently determine …

Toward a Spatiotemporal Understanding of Dolomite Dissolution in Sandstone by CO2-Enriched Brine Circulation

J Ma, L Querci, B Hattendorf, MO Saar… - … science & technology, 2019 - ACS Publications
In this study, we introduce a stochastic method to delineate the mineral effective surface
area (ESA) evolution during a recycling reactive flow-through transport experiment on a …

A Lagrangian method for reactive transport with solid/aqueous chemical phase interaction

MJ Schmidt, SD Pankavich, A Navarre-Sitchler… - Journal of …, 2019 - Elsevier
A significant drawback of Lagrangian (particle-tracking) reactive transport models has been
their inability to properly simulate interactions between solid and liquid chemical phases …

Towards a Universal Scaling Method for Predicting Equilibrium Constants of Polyoxometalates

J Buils, D Garay-Ruiz, E Petrus, M Segado-Centellas… - 2024 - chemrxiv.org
The computational prediction of equilibrium constants is still an open problem for a wide
variety of relevant chemical systems. Particularly, acid dissociation constants (pKa) are an …

[КНИГА][B] Lagrangian Methods for Modeling Transport, Mixing, and Geochemical Reactions

M Schmidt - 2019 - search.proquest.com
This thesis is concerned with methods for enhancing the current capabilities of Lagrangian
(particle-tracking) methods for modeling transport, mixing, and geochemical reactions. We …