The calculation of rate coefficients is a discipline of nonlinear science of importance to much
of physics, chemistry, engineering, and biology. Fifty years after Kramers' seminal paper on …

Some of the rate theories that are most useful for modeling biological processes are
reviewed. By delving into some of the details and subtleties in the development of the …

We present a molecular model for studying the prototypical ferric–ferrous electron transfer
process in liquid water, and we discuss its structural implications. Treatment of the …

By use of an adiabatic elimination procedure and a time scaling t^= τ− 1/2 t, where τ denotes
the correlation time of colored noise ɛ (t), one arrives at a novel colored-noise …

The calculationof chemical reaction rate constants is of importance to much of chemistry and
biology. Here we present our current understanding of the physical principles determining …

A brief history is presented, outlining the development of rate theory during the past century.
Starting from Arrhenius [Z. Phys. Chem. 4, 226 (1889)], we follow especially the formulation …

An analytical theory is formulated for the thermal (classical mechanical) rate of escape from
a metastable state coupled to a dissipative thermal environment. The working expressions …

It has become standard practice to describe systems that remain far from equilibrium even in
their steady state by Langevin equations with colored noise which is chosen independently …

Viscoelastic subdiffusion: generalized Langevin equation approach Page 195 VISCOELASTIC
SUBDIFFUSION: GENERALIZED LANGEVIN EQUATION APPROACH IGOR GOYCHUK …

Molecular dynamics (MD) simulations of the model SN2 reaction Cl−+ CH3Cl→ ClCH3+ Cl−
in water, and variants thereof, are presented. The resulting transmission coefficients κ, that …