Chemical flexibility of atomically precise metal clusters

S Li, NN Li, XY Dong, SQ Zang, TCW Mak - Chemical Reviews, 2024 - ACS Publications
Ligand-protected metal clusters possess hybrid properties that seamlessly combine an
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …

Recent developments in the investigation of driving forces for transforming coinage metal nanoclusters

X Zou, X Kang, M Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal nanoclusters serve as an emerging class of modular nanomaterials. The
transformation of metal nanoclusters has been fully reflected in their studies from every …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R ** - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Mediating CO2 Electroreduction Activity and Selectivity over Atomically Precise Copper Clusters

LJ Liu, ZY Wang, ZY Wang, R Wang… - Angewandte …, 2022 - Wiley Online Library
Atomically precise copper clusters are highly desirable catalysts for electrocatalytic CO2
reduction reaction (CO2RR) and provide an ideal platform for elaborating structure–activity …

Do**‐Mediated Energy‐Level Engineering of M@Au12 Superatoms (M=Pd, Pt, Rh, Ir) for Efficient Photoluminescence and Photocatalysis

H Hirai, S Takano, T Nakashima… - Angewandte Chemie …, 2022 - Wiley Online Library
We synthesized a series of MAu12 (dppe) 5Cl2 (MAu12; M= Au, Pd, Pt, Rh, or Ir; dppe= 1, 2‐
bis (diphenylphosphino) ethane), which have icosahedral M@ Au12 superatomic cores, and …

Chemically modified gold/silver superatoms as artificial elements at nanoscale: design principles and synthesis challenges

S Takano, T Tsukuda - Journal of the American Chemical Society, 2021 - ACS Publications
Pure and doped gold/silver clusters protected by monolayers of organic ligands have
attracted much interest as novel functional materials owing to their nonbulk-like, size-specific …

Catalysis synergism by atomically precise bimetallic nanoclusters doped with heteroatoms

X Liu, X Cai, Y Zhu - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Bimetallic catalysts hold promise in tailoring the catalytic activity and selectivity
of transition metals for important chemical processes due to the synergistic coupling …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J **e - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Hydrido-coinage-metal clusters: Rational design, synthetic protocols and structural characteristics

C Sun, BK Teo, C Deng, J Lin, GG Luo, CH Tung… - Coordination Chemistry …, 2021 - Elsevier
Ligated hydrido-coinage-metal clusters M x H y L z (M= Cu/Ag/Au, L= ligand; where x, y, and
z are positive integers) often exhibit interesting catalytic properties, and serve as ideal …

Nanocluster Transformation Induced by SbF6 Anions toward Boosting Photochemical Activities

X Wei, K Chu, JR Adsetts, H Li, X Kang… - Journal of the …, 2022 - ACS Publications
The interactions between SbF6–and metal nanoclusters are of significance for customizing
clusters from both structure and property aspects; however, the whole-segment monitoring of …