The active phase in cobalt-based Fischer-Tropsch synthesis

IC ten Have, BM Weckhuysen - Chem Catalysis, 2021‏ - cell.com
Fischer-Tropsch synthesis (FTS) is an industrial catalytic process that converts a mixture of
CO and hydrogen into long-chain hydrocarbons. These products are used as clean …

Recent advances in understanding the key catalyst factors for Fischer-Tropsch synthesis

Q Zhang, W Deng, Y Wang - Journal of Energy Chemistry, 2013‏ - Elsevier
Catalytic conversion of synthesis gas (CO+ H2) into hydrocarbons, also known as Fischer-
Tropsch (FT) synthesis, is a crucial reaction for the transformation of non-petroleum carbon …

High alcohols synthesis via Fischer–Tropsch reaction at cobalt metal/carbide interface

YP Pei, JX Liu, YH Zhao, YJ Ding, T Liu, WD Dong… - ACS …, 2015‏ - ACS Publications
Utilization of nonprecious transition metals for high alcohols synthesis is of a great
importance in heterogeneous catalysis. We synthesized successfully cobalt metal-carbide …

Tuning the interaction between Na and Co2C to promote selective CO2 hydrogenation to ethanol

S Zhang, Z Wu, X Liu, Z Shao, L **a, L Zhong… - Applied Catalysis B …, 2021‏ - Elsevier
Direct CO 2 hydrogenation to ethanol is one of the promising alternatives to realize “carbon-
neutral” protocol. However, stabilizing catalyst structure and modulating CO activation …

Direct CO2 hydrogenation to ethanol over supported Co2C catalysts: Studies on support effects and mechanism

S Zhang, X Liu, Z Shao, H Wang, Y Sun - Journal of Catalysis, 2020‏ - Elsevier
Direct CO 2 hydrogenation to ethanol is one of the promising and emerging routes for the
transformation of CO 2 into value-added chemicals, but it remains a major challenge …

Large‐Scale Synthesis of Multifunctional Single‐Phase Co2C Nanomaterials

Z Yang, T Zhao, S Hao, R Wang, C Zhu… - Advanced …, 2023‏ - Wiley Online Library
Achieving scalable synthesis of nanoscale transition‐metal carbides (TMCs), regarded as
substitutes for platinum‐group noble metals, remains an ongoing challenge. Herein, a 100 …

Double-atom dealloying-derived Frank partial dislocations in cobalt nanocatalysts boost metal–air batteries and fuel cells

T Meng, P Sun, F Yang, J Zhu, B Mao, L Zheng… - Proceedings of the …, 2022‏ - pnas.org
Oxygen reduction reaction (ORR), an essential reaction in metal–air batteries and fuel cells,
still faces many challenges, such as exploiting cost-effective nonprecious metal …

In situ magnetometer study on the formation and stability of cobalt carbide in Fischer–Tropsch synthesis

M Claeys, ME Dry, E Van Steen, E Du Plessis… - Journal of catalysis, 2014‏ - Elsevier
While carbides are always present in iron-based Fischer–Tropsch synthesis, very little is
known about the presence and the role of carbides in cobalt-based CO hydrogenation …

Visualizing Phase Evolution of Co2C for Efficient Fischer–Tropsch to Olefins

X Hong, Q Zhao, Y Chen, Z Yu, M Zhou… - Advanced …, 2024‏ - Wiley Online Library
Cobalt carbide (Co2C) possesses high catalytic efficiency Fischer–Tropsch synthesis (FTS),
while the products selectivity appears sensitive to crystallography geometry. Since the …

Metallic Co2C: A Promising Co-catalyst To Boost Photocatalytic Hydrogen Evolution of Colloidal Quantum Dots

Q Guo, F Liang, XY Gao, QC Gan, XB Li, J Li… - ACS …, 2018‏ - ACS Publications
Transition-metal carbide (TMC), because of its electronic conductivity, chemical stability, and
physical properties, has aroused widespread interest in catalysis. Here, we have …