Recent advances in synthesis strategies for biomass-derived high-energy-density jet fuels

Z Fang, X Zhang, X Zhuang, L Ma - Renewable and Sustainable Energy …, 2024 - Elsevier
High-energy-density jet fuels enable volume/weight-limited aircraft to exhibit a higher speed,
payload, and flying range. Lignocellulosic biomass, with renewability and sustainability, has …

Total synthesis of cyclopropane-containing natural products: recent progress (2016–2024)

N Wang, JX Zhao, JM Yue - Organic Chemistry Frontiers, 2025 - pubs.rsc.org
Cyclopropane, as the smallest all-carbon ring, is a ubiquitous functional group found in
many complex natural products, such as terpenoids, alkaloids, steroids, and fatty acids …

Tridentate Bromo-Substituted Porphyrin-Based Metal–Organic Framework Nanoflowers for Alkene Cyclopropanation

Y Wang, H Lin, W Deng, C Chen… - ACS Applied Nano …, 2025 - ACS Publications
Ultrathin two-dimensional (2D) metal–organic frameworks have exhibited powerful potential
in heterogeneous catalysis due to their abundant exposed active sites. Herein, we report the …

Organozinc Reagents: Highly Efficient Scalable Continuous Conversion in Various Concentrations and Reaction Types

L Gössl, K Dahms, G Menges-Flanagan… - … Process Research & …, 2024 - ACS Publications
Organometallic reagents play a crucial role in today's synthetic chemistry. They are used in
the production of active pharmaceutical ingredients (APIs), fragrances, and agrochemicals …

Continuous Scalable Synthesis and Concentration Variation of Organozinc Compounds

L Gössl, K Dahms, G Menges-Flanagan… - … Process Research & …, 2024 - ACS Publications
In the production of pharmaceutically active ingredients, the formation of new carbon–
carbon bonds is essential. A widespread and frequently employed method is the use of …

Development of a Scalable Process for the Synthesis of Cyclopropyl-Methyl-Proline with Complex Stereochemistry: A Key Building Block of Factor D Inhibitors

A Hashimoto, AC Ferretti, SK Tipparaju… - … Process Research & …, 2024 - ACS Publications
The development of a scalable process for a complex intermediate featuring a chiral,
quaternary cyclopropane moiety presented significant challenges. We report two …

Unveiling the Beauty of Cyclopropane Formation: A Comprehensive Survey of Enantioselective Michael Initiated Ring Closure (MIRC) Reactions

R Moorthy, W Biosawe, SS Thorat… - Organic Chemistry …, 2024 - pubs.rsc.org
This review presents a comprehensive overview of the synthesis of cyclopropanes using
enantioselective Michael Initiated Ring Closure (MIRC) reaction. Cyclopropane-containing …

New functionally substitutes cyclopropanecarboxylic acids as ethylene biosynthesis innovative regulators

A Mikaelyan, S Bagdasaryan, B Babayan… - Bioactive Compounds in …, 2024 - ffhdj.com
Background: Derivatives of small carbocycles (cyclobutanes and cyclopropanes) are known
as bioactive molecules. Both their natural and synthetic representatives have multiple …

Flow Chemistry of Metal Carbenoid Species towards Selective Organic Synthesis

K Okamoto, A Nagaki - Synthesis, 2024 - thieme-connect.com
This review deals with C1 carbenoid chemistry, with a focus on lithium carbenoid species
generated in flash flow systems. Strict control of the temperature, residence time, and mixing …

Aryl‐Fluorocyclopropane β‐Lactams with Activity Against Mycobacteroides abscessus and Mycobacterium bovis BCG

DE Spurling, EJ Baker… - European Journal of …, 2025 - Wiley Online Library
A novel series of aryl‐α‐fluorocyclopropyl 1 and α, β, β‐trifluorocyclopropyl 2 β‐lactams
have been prepared and their activity explored across various Mycobacteria and also the …