Recent progress and prospects in catalytic water treatment
Presently, conventional technologies in water treatment are not efficient enough to
completely mineralize refractory water contaminants. In this context, the implementation of …
completely mineralize refractory water contaminants. In this context, the implementation of …
Status of reactive non-heme metal–oxygen intermediates in chemical and enzymatic reactions
Selective functionalization of unactivated C–H bonds, water oxidation, and dioxygen
reduction are extremely important reactions in the context of finding energy carriers and …
reduction are extremely important reactions in the context of finding energy carriers and …
Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C–H activation
Since our initial report in 1976, the oxygen rebound mechanism has become the consensus
mechanistic feature for an expanding variety of enzymatic C–H functionalization reactions …
mechanistic feature for an expanding variety of enzymatic C–H functionalization reactions …
Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants
S Kal, L Que - JBIC Journal of Biological Inorganic Chemistry, 2017 - Springer
Abstract The 2-His-1-carboxylate facial triad is a widely used scaffold to bind the iron center
in mononuclear nonheme iron enzymes for activating dioxygen in a variety of oxidative …
in mononuclear nonheme iron enzymes for activating dioxygen in a variety of oxidative …
Versatility of biological non-heme Fe (II) centers in oxygen activation reactions
EG Kovaleva, JD Lipscomb - Nature chemical biology, 2008 - nature.com
Oxidase and oxygenase enzymes allow the use of relatively unreactive O2 in biochemical
reactions. Many of the mechanistic strategies used in nature for this key reaction are …
reactions. Many of the mechanistic strategies used in nature for this key reaction are …
The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes
J Hohenberger, K Ray, K Meyer - Nature communications, 2012 - nature.com
Selective functionalization of unactivated C–H bonds and ammonia production are
extremely important industrial processes. A range of metalloenyzmes achieve these …
extremely important industrial processes. A range of metalloenyzmes achieve these …
Enzyme-mediated oxidations for the chemist
Biocatalysis is an enabling technology adding to organic oxidation chemistry. Especially the
high selectivity of enzymatic oxidation coevally operating under mild conditions and not …
high selectivity of enzymatic oxidation coevally operating under mild conditions and not …
Mononuclear non-heme iron enzymes with the 2-His-1-carboxylate facial triad: recent developments in enzymology and modeling studies
PCA Bruijnincx, G van Koten… - Chemical Society …, 2008 - pubs.rsc.org
Iron-containing enzymes are one of Nature's main means of effecting key biological
transformations. The mononuclear non-heme iron oxygenases and oxidases have received …
transformations. The mononuclear non-heme iron oxygenases and oxidases have received …
Mechanism and catalytic diversity of Rieske non-heme iron-dependent oxygenases
SM Barry, GL Challis - ACS catalysis, 2013 - ACS Publications
Rieske non-heme iron-dependent oxygenases are important enzymes that catalyze a wide
variety of reactions in the biodegradation of xenobiotics and biosynthesis of bioactive natural …
variety of reactions in the biodegradation of xenobiotics and biosynthesis of bioactive natural …
Dichotomous hydrogen atom transfer vs proton-coupled electron transfer during activation of X–H bonds (X= C, N, O) by nonheme iron–oxo complexes of variable …
We describe herein the hydrogen-atom transfer (HAT)/proton-coupled electron-transfer
(PCET) reactivity for FeIV–oxo and FeIII–oxo complexes (1–4) that activate C–H, N–H, and O …
(PCET) reactivity for FeIV–oxo and FeIII–oxo complexes (1–4) that activate C–H, N–H, and O …