Reactions of hydrosilanes with transition metal complexes and characterization of the products
JY Corey - Chemical Reviews, 2011 - ACS Publications
Hydrosilanes are used as versatile coreactants in the generation of silyl-metal complexes.
Since organohydrosilanes may contain one, two, or three SiH bonds as tertiary, secondary …
Since organohydrosilanes may contain one, two, or three SiH bonds as tertiary, secondary …
The transition-metal chemistry of amidinatosilylenes,-germylenes and-stannylenes
L Álvarez-Rodríguez, JA Cabeza… - Coordination Chemistry …, 2015 - Elsevier
The transition-metal (TM) chemistry of heavier tetrylenes (HTs), also known as heavier
carbene analogs, group 14 metalenes or group 14 metalylenes (compounds containing Si …
carbene analogs, group 14 metalenes or group 14 metalylenes (compounds containing Si …
Experimental and Computational Studies on Remote γ-C(sp3)–H Silylation and Germanylation of Aliphatic Carboxamides
A Pd (II)-catalyzed protocol for highly regioselective distal γ-C–H silylation and
germanylation of aliphatic carboxylic acids is reported. Bidentate 8-aminoquinoline as the …
germanylation of aliphatic carboxylic acids is reported. Bidentate 8-aminoquinoline as the …
[PDF][PDF] Synthesis and Unexpected Coordination of a Silicon (II)‐Based SiCSi Pincerlike Arene to Palladium
Chelate ligands can be important for steering the reactivity of transition-metal complexes.
Among multidentate ligands, pincer arenes, consisting of a central aromatic backbone linked …
Among multidentate ligands, pincer arenes, consisting of a central aromatic backbone linked …
Si–H bond activation at {(NHC) 2 Ni 0} leading to hydrido silyl and bis (silyl) complexes: a versatile tool for catalytic Si–H/D exchange, acceptorless dehydrogenative …
D Schmidt, T Zell, T Schaub, U Radius - Dalton Transactions, 2014 - pubs.rsc.org
The unique reactivity of the nickel (0) complex [Ni2 (iPr2Im) 4 (COD)](1)(iPr2Im= 1, 3-di-
isopropyl-imidazolin-2-ylidene) towards hydrosilanes in stoichiometric and catalytic …
isopropyl-imidazolin-2-ylidene) towards hydrosilanes in stoichiometric and catalytic …
Triangular palladium cluster from activation of the Si–Si bond in a disilane with phosphine pendants
R Usui, Y Sunada - Inorganic Chemistry, 2021 - ACS Publications
A disilane that contains two diphenylphosphino moieties,(Ph2PCH2) Ph2Si–SiPh2
(CH2PPh), was readily synthesized from the reaction of ClPh2Si–SiPh2Cl with (tmeda) Li …
(CH2PPh), was readily synthesized from the reaction of ClPh2Si–SiPh2Cl with (tmeda) Li …
Higher-coordinated molecular silicon compounds
In silicon compounds the Si atoms are known to be fourfold coordinated in most cases.
However, there are several cationic, anionic, and neutral molecular species containing …
However, there are several cationic, anionic, and neutral molecular species containing …
Multinuclear Pd and Pt complexes with bridging Si-and Ge-ligands. Stable and flexible coordination bonds and structures and reactions of the molecules
Late transition metal complexes with metal-silicon or metal-germanium σsingle bondbond
show the chemical properties that could not be found for the complexes with metal-carbon …
show the chemical properties that could not be found for the complexes with metal-carbon …
Synthesis and structures of (dialkylsilylene) bis (phosphine)-nickel, palladium, and platinum complexes and (η 6-arene)(dialkylsilylene) nickel complexes
C Watanabe, Y Inagawa, T Iwamoto, M Kira - Dalton Transactions, 2010 - pubs.rsc.org
A series of dialkylsilylene-group 10 metal complexes (RH2Si)(Me3P) 2M (M= Ni, Pd, Pt,
RH2= 1, 1, 4, 4-tetrakis (trimethylsilyl) butane-1, 4-diyl) and novel (η6-arene)(dialkylsilylene) …
RH2= 1, 1, 4, 4-tetrakis (trimethylsilyl) butane-1, 4-diyl) and novel (η6-arene)(dialkylsilylene) …
Dimensionality Expansion of a Butterfly Shaped Pd4 Framework: Constructing Edge‐Sharing Pd6 Tetrahedra
K Shimamoto, Y Sunada - Chemistry–A European Journal, 2019 - Wiley Online Library
The construction of well‐defined transition‐metal clusters has attracted substantial attention
due to their unique chemical and/or physical properties. Metal clusters with 1D or 2D …
due to their unique chemical and/or physical properties. Metal clusters with 1D or 2D …