Metal–organic frameworks and covalent organic frameworks as disruptive membrane materials for energy-efficient gas separation

AA Knebel, J Caro - Nature Nanotechnology, 2022 - nature.com
In this Review we survey the molecular sieving behaviour of metal–organic framework
(MOF) and covalent organic framework (COF) membranes, which is different from that of …

Two-dimensional conjugated metal–organic frameworks (2D c-MOFs): chemistry and function for MOFtronics

M Wang, R Dong, X Feng - Chemical Society Reviews, 2021 - pubs.rsc.org
The 21st century has seen a reinvention of how modern electronics impact our daily lives;
silicon-electronics and organic electronics are currently at the core of modern electronics …

Hydrogen bonding regulated flexibility and disorder in hydrazone-linked covalent organic frameworks

Y Li, J Sui, LS Cui, HL Jiang - Journal of the American Chemical …, 2023 - ACS Publications
Covalent organic framework (COF) chemistry is experiencing unprecedented development
in recent decades. The current studies on COF chemistry are mainly focused on the …

Covalent organic framework atropisomers with multiple gas-triggered structural flexibilities

C Kang, Z Zhang, S Kusaka, K Negita, AK Usadi… - Nature Materials, 2023 - nature.com
Covalent organic frameworks (COFs) are emerging crystalline porous polymers, showing
great potential for applications but lacking gas-triggered flexibility. Atropisomerism was …

Ethylene/ethane separation in a stable hydrogen-bonded organic framework through a gating mechanism

Y Yang, L Li, RB Lin, Y Ye, Z Yao, L Yang, F **ang… - Nature Chemistry, 2021 - nature.com
Porous materials are very promising for the development of cost-and energy-efficient
separation processes, such as for the purification of ethylene from ethylene/ethane mixture …

Destruction of metal–organic frameworks: positive and negative aspects of stability and lability

L Feng, KY Wang, GS Day, MR Ryder… - Chemical …, 2020 - ACS Publications
Metal–organic frameworks (MOFs), constructed from organic linkers and inorganic building
blocks, are well-known for their high crystallinity, high surface areas, and high component …

Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system

I Senkovska, V Bon, L Abylgazina, M Mendt… - Angewandte …, 2023 - Wiley Online Library
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …

Metal–organic frameworks as a platform for clean energy applications

X Li, X Yang, H Xue, H Pang, Q Xu - EnergyChem, 2020 - Elsevier
Abstract Metal–organic frameworks (MOFs), an emerging class of porous materials, have
shown intriguing and promising properties in a wide range of applications due to their …

A reticular chemistry guide for the design of periodic solids

H Jiang, D Alezi, M Eddaoudi - Nature Reviews Materials, 2021 - nature.com
Reticular chemistry—the linking of well-defined molecular building blocks by strong bonds
into crystalline extended frameworks—has enabled the synthesis of diverse metal–organic …

Microporous metal-organic framework materials for gas separation

RB Lin, S **ang, W Zhou, B Chen - Chem, 2020 - cell.com
Gas separation is a very important industrial process for manufacturing chemicals, fuels,
plastics, and polymers but is also energy intensive through the traditional cryogenic …