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Structure, properties and reactivity of polyoxometalates: a theoretical perspective
In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …
Decoupling hydrogen and oxygen evolution during electrolytic water splitting using an electron-coupled-proton buffer
Hydrogen is essential to several key industrial processes and could play a major role as an
energy carrier in a future 'hydrogen economy'. Although the majority of the world's hydrogen …
energy carrier in a future 'hydrogen economy'. Although the majority of the world's hydrogen …
Tuning and mechanistic insights of metal chalcogenide molecular catalysts for the hydrogen-evolution reaction
The production of hydrogen through water splitting using earth-abundant metal catalysts is a
promising pathway for converting solar energy into chemical fuels. However, existing …
promising pathway for converting solar energy into chemical fuels. However, existing …
Soluble hetero‐polyoxovanadates and their solution chemistry analyzed by electrospray ionization mass spectrometry
Polyoxometalates (POMs) are an intriguing class of compounds due to their tremendous
structural variety and the wide spectrum of resulting properties, which make them interesting …
structural variety and the wide spectrum of resulting properties, which make them interesting …
Solar Light CO2 Photoreduction Enhancement by Mononuclear Rhenium(I) Complexes: Characterization and Mechanistic Insights
The catalytic efficacy of a novel mononuclear rhenium (I) complex in CO2 reduction is
remarkable, with a turnover number (TONCO) of 1517 in 3 h, significantly outperforming …
remarkable, with a turnover number (TONCO) of 1517 in 3 h, significantly outperforming …
Experimental and Theoretical Investigation of the Mechanism of the Reduction of O2 from Air to O22– by VIVO2+–N,N,N-Amidate Compounds and Their …
M Papanikolaou, S Hadjithoma, O Keramidas… - Inorganic …, 2024 - ACS Publications
The two-electron reductive activation of O2 to O22–is of particular interest to the scientific
community mainly due to the use of peroxides as green oxidants and in powerful fuel cells …
community mainly due to the use of peroxides as green oxidants and in powerful fuel cells …
A Lacunary Polyoxovanadate Precursor and Transition‐Metal‐Sandwiched Derivatives for Catalytic Oxidation of Sulfides
R Wan, P He, Z Liu, X Ma, P Ma, V Singh… - … A European Journal, 2020 - Wiley Online Library
A SeO3‐centered lacunary Keggin‐type heteropolyoxovanadate (hetero‐POV) K6H2
[SeV10O28 (SeO3) 3]⋅ 14 H2O (1) was isolated by one‐pot reaction of KVO3 and SeO2 …
[SeV10O28 (SeO3) 3]⋅ 14 H2O (1) was isolated by one‐pot reaction of KVO3 and SeO2 …
Manipulating the supramolecular assembly of γ-cyclodextrin and Anderson polyoxometalate hybrids through variations in remote functionality
YA Yin, WJ Chen, CY Liu, MM Zhang, CG Lin… - Cell Reports Physical …, 2024 - cell.com
Understanding and controlling the primary interactions between molecule-based building
blocks is of fundamental importance to design hierarchical supramolecular assemblies at …
blocks is of fundamental importance to design hierarchical supramolecular assemblies at …
Oscillatory template exchange in polyoxometalate capsules: a ligand-triggered, redox-powered, chemically damped oscillation
HN Miras, M Sorus, J Hawkett, DO Sells… - Journal of the …, 2012 - ACS Publications
The redox-controlled driven oscillatory template exchange between phosphate (P) and
vanadate (V) anions enclosed in an {X2M18} cluster is reported. Extensive investigations …
vanadate (V) anions enclosed in an {X2M18} cluster is reported. Extensive investigations …
Trap** the δ isomer of the polyoxometalate‐based keggin Cluster with a tripodal ligand
We report the synthesis, structural, and electronic characterization of the theoretically
predicted, but experimentally elusive δ‐isomer of the Keggin polyoxometalate polyanion. A …
predicted, but experimentally elusive δ‐isomer of the Keggin polyoxometalate polyanion. A …