Structure, properties and reactivity of polyoxometalates: a theoretical perspective

X López, JJ Carbó, C Bo, JM Poblet - Chemical Society Reviews, 2012 - pubs.rsc.org
In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …

Decoupling hydrogen and oxygen evolution during electrolytic water splitting using an electron-coupled-proton buffer

MD Symes, L Cronin - Nature chemistry, 2013 - nature.com
Hydrogen is essential to several key industrial processes and could play a major role as an
energy carrier in a future 'hydrogen economy'. Although the majority of the world's hydrogen …

Tuning and mechanistic insights of metal chalcogenide molecular catalysts for the hydrogen-evolution reaction

J McAllister, NAG Bandeira, JC McGlynn… - Nature …, 2019 - nature.com
The production of hydrogen through water splitting using earth-abundant metal catalysts is a
promising pathway for converting solar energy into chemical fuels. However, existing …

Soluble hetero‐polyoxovanadates and their solution chemistry analyzed by electrospray ionization mass spectrometry

U Warzok, LK Mahnke, W Bensch - Chemistry–A European …, 2019 - Wiley Online Library
Polyoxometalates (POMs) are an intriguing class of compounds due to their tremendous
structural variety and the wide spectrum of resulting properties, which make them interesting …

Solar Light CO2 Photoreduction Enhancement by Mononuclear Rhenium(I) Complexes: Characterization and Mechanistic Insights

MA Bento, NAG Bandeira, HN Miras, AJ Moro… - Inorganic …, 2024 - ACS Publications
The catalytic efficacy of a novel mononuclear rhenium (I) complex in CO2 reduction is
remarkable, with a turnover number (TONCO) of 1517 in 3 h, significantly outperforming …

Experimental and Theoretical Investigation of the Mechanism of the Reduction of O2 from Air to O22– by VIVO2+N,N,N-Amidate Compounds and Their …

M Papanikolaou, S Hadjithoma, O Keramidas… - Inorganic …, 2024 - ACS Publications
The two-electron reductive activation of O2 to O22–is of particular interest to the scientific
community mainly due to the use of peroxides as green oxidants and in powerful fuel cells …

A Lacunary Polyoxovanadate Precursor and Transition‐Metal‐Sandwiched Derivatives for Catalytic Oxidation of Sulfides

R Wan, P He, Z Liu, X Ma, P Ma, V Singh… - … A European Journal, 2020 - Wiley Online Library
A SeO3‐centered lacunary Keggin‐type heteropolyoxovanadate (hetero‐POV) K6H2
[SeV10O28 (SeO3) 3]⋅ 14 H2O (1) was isolated by one‐pot reaction of KVO3 and SeO2 …

Manipulating the supramolecular assembly of γ-cyclodextrin and Anderson polyoxometalate hybrids through variations in remote functionality

YA Yin, WJ Chen, CY Liu, MM Zhang, CG Lin… - Cell Reports Physical …, 2024 - cell.com
Understanding and controlling the primary interactions between molecule-based building
blocks is of fundamental importance to design hierarchical supramolecular assemblies at …

Oscillatory template exchange in polyoxometalate capsules: a ligand-triggered, redox-powered, chemically damped oscillation

HN Miras, M Sorus, J Hawkett, DO Sells… - Journal of the …, 2012 - ACS Publications
The redox-controlled driven oscillatory template exchange between phosphate (P) and
vanadate (V) anions enclosed in an {X2M18} cluster is reported. Extensive investigations …

Trap** the δ isomer of the polyoxometalate‐based keggin Cluster with a tripodal ligand

H Sartzi, HN Miras, L Vilà‐Nadal… - Angewandte Chemie …, 2015 - Wiley Online Library
We report the synthesis, structural, and electronic characterization of the theoretically
predicted, but experimentally elusive δ‐isomer of the Keggin polyoxometalate polyanion. A …