Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications

AV Anyushin, A Kondinski, TN Parac-Vogt - Chemical Society Reviews, 2020 - pubs.rsc.org
Polyoxometalates (POMs) represent an important group of metal–oxo nanoclusters, typically
comprised of early transition metals in high oxidation states (mainly V, Mo and W). Many …

Synthesis, structures and applications of electron-rich polyoxometalates

NI Gumerova, A Rompel - Nature Reviews Chemistry, 2018 - nature.com
Ever since the discovery and development of polyoxometalates (POMs), it has been known
that they can exist in electron-rich reduced forms of different archetypes, structural …

Dioxygen in polyoxometalate mediated reactions

IA Weinstock, RE Schreiber, R Neumann - Chemical reviews, 2017 - ACS Publications
In this review article, we consider the use of molecular oxygen in reactions mediated by
polyoxometalates. Polyoxometalates are anionic metal oxide clusters of a variety of …

The molybdenum blue reaction for the determination of orthophosphate revisited: Opening the black box

EA Nagul, ID McKelvie, P Worsfold, SD Kolev - Analytica chimica acta, 2015 - Elsevier
The molybdenum blue reaction, used predominantly for the determination of orthophosphate
in environmental waters, has been perpetually modified and re-optimised over the years, but …

CsPbBr3/Polyoxometalate Composites for Selective Photocatalytic Oxidation of Benzyl Alcohol

Y Dong, Y Feng, Z Li, H Zhou, H Lv, GY Yang - ACS Catalysis, 2023 - ACS Publications
Selective oxidation of benzyl alcohols to the corresponding carbonyl compounds is of great
importance for providing versatile intermediates for the synthesis of pharmaceuticals and …

Structure, properties and reactivity of polyoxometalates: a theoretical perspective

X López, JJ Carbó, C Bo, JM Poblet - Chemical Society Reviews, 2012 - pubs.rsc.org
In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …

Fe‐doped Polyoxometalate as acid‐aggregated Nanoplatform for NIR‐II Photothermal‐enhanced Chemodynamic therapy

Y Shi, J Zhang, H Huang, C Cao, J Yin… - Advanced …, 2020 - Wiley Online Library
The combination of reactive oxygen species‐involved chemodynamic therapy (CDT) and
photothermal therapy (PTT) holds great promise in enhancing anticancer effects. Herein, a …

Polyoxometalate‐Structured Materials: Molecular Fundamentals and Electrocatalytic Roles in Energy Conversion

T Ma, R Yan, X Wu, M Wang, B Yin, S Li… - Advanced …, 2024 - Wiley Online Library
Polyoxometalates (POMs), a kind of molecular metal oxide cluster with unique physical–
chemical properties, have made essential contributions to creating efficient and robust …

A polyoxometalate cluster paradigm with self-adaptive electronic structure for acidity/reducibility-specific photothermal conversion

C Zhang, W Bu, D Ni, C Zuo, C Cheng… - Journal of the …, 2016 - ACS Publications
Photothermal conversion is one of the most important keys in the fields of solar collection,
photo-hyperthermia, etc., and its performance is highly dependent on the photothermal …

Electrochemistry of polyoxometalates: from fundamental aspects to applications

T Ueda - ChemElectroChem, 2018 - Wiley Online Library
Electrochemistry of polyoxometalates is very rich, as many of them can accommodate many
electrons without their structure changing. Recently, extensive attention has been paid to the …