Cation-disordered rocksalt transition metal oxides and oxyfluorides for high energy lithium-ion cathodes

RJ Clément, Z Lun, G Ceder - Energy & Environmental Science, 2020 - pubs.rsc.org
For lithium-ion rechargeable batteries to meet society's ever-growing demands in electrical
energy storage, eg for the electrification of transportation, for portable electronics and for grid …

A review of Ni-based layered oxides for rechargeable Li-ion batteries

J Xu, F Lin, MM Doeff, W Tong - Journal of Materials Chemistry A, 2017 - pubs.rsc.org
The portable electronic market, vehicle electrification (electric vehicles or EVs) and grid
electricity storage impose strict performance requirements on Li-ion batteries, the energy …

Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries

N Yabuuchi, M Nakayama, M Takeuchi… - Nature …, 2016 - nature.com
Further increase in energy density of lithium batteries is needed for zero emission vehicles.
However, energy density is restricted by unavoidable theoretical limits for positive electrodes …

Manipulating disorder within cathodes of alkali-ion batteries

S Kang, S Lee, H Lee, YM Kang - Nature Reviews Chemistry, 2024 - nature.com
The fact that ordered materials are rarely perfectly crystalline is widely acknowledged
among materials scientists, but its impact is often overlooked or underestimated when …

A near dimensionally invariable high-capacity positive electrode material

I Konuma, D Goonetilleke, N Sharma, T Miyuki… - Nature Materials, 2023 - nature.com
Delivering inherently stable lithium-ion batteries is a key challenge. Electrochemical lithium
insertion and extraction often severely alters the electrode crystal chemistry, and this …

Nanoscale phenomena in lithium-ion batteries

SK Jung, I Hwang, D Chang, KY Park, SJ Kim… - Chemical …, 2019 - ACS Publications
The electrochemical properties and performances of lithium-ion batteries are primarily
governed by their constituent electrode materials, whose intrinsic thermodynamic and kinetic …

Redox Chemistry and the Role of Trapped Molecular O2 in Li-Rich Disordered Rocksalt Oxyfluoride Cathodes

R Sharpe, RA House, MJ Clarke… - Journal of the …, 2020 - ACS Publications
In the search for high energy density cathodes for next-generation lithium-ion batteries, the
disordered rocksalt oxyfluorides are receiving significant attention due to their high capacity …

Lithium manganese oxyfluoride as a new cathode material exhibiting oxygen redox

RA House, L **, U Maitra, K Tsuruta… - Energy & …, 2018 - pubs.rsc.org
The quantity of charge stored in transition metal oxide intercalation cathodes for Li or Na
batteries is not limited by transition metal redox reactions but can also access redox …

An overview of cation-disordered lithium-excess rocksalt cathodes

D Chen, J Ahn, G Chen - ACS Energy Letters, 2021 - ACS Publications
In the past several years, cation-disordered Li-excess rocksalts (DRXs) have quickly
emerged as a new class of promising high-energy Li-ion battery (LIB) cathode materials …

A new class of high capacity cation-disordered oxides for rechargeable lithium batteries: Li–Ni–Ti–Mo oxides

J Lee, DH Seo, M Balasubramanian, N Twu… - Energy & …, 2015 - pubs.rsc.org
Recent successes with disordered Li-excess materials and applications of percolation
theory have highlighted cation-disordered oxides as high capacity and energy density …