Effects of confinement on material behaviour at the nanometre size scale
In this article, the effects of size and confinement at the nanometre size scale on both the
melting temperature, T m, and the glass transition temperature, T g, are reviewed. Although …
melting temperature, T m, and the glass transition temperature, T g, are reviewed. Although …
Polymer-silicate nanocomposites: model systems for confined polymers and polymer brushes
The static and dynamic properties of polymer-layered silicate nanocomposites are
discussed, in the context of polymers in confined spaces and polymer brushes. A wide range …
discussed, in the context of polymers in confined spaces and polymer brushes. A wide range …
Structure and dynamics of polymer-layered silicate nanocomposites
The static and dynamic properties of polymer-layered silicate nanocomposites are
discussed in the context of polymers in confined media. Despite the topological constraints …
discussed in the context of polymers in confined media. Despite the topological constraints …
Interface and surface effects on the glass transition in thin polystyrene films
GB DeMaggio, WE Frieze, DW Gidley, M Zhu… - Physical Review Letters, 1997 - APS
Lifetime analysis of positronium annihilating in nanometer voids is used to study the thermal
expansion behavior of thin, Si-supported polystyrene films near the glass transition …
expansion behavior of thin, Si-supported polystyrene films near the glass transition …
Thermal analysis of the double‐melting behavior of poly(L‐lactic acid)
M Yasuniwa, S Tsubakihara… - Journal of Polymer …, 2004 - Wiley Online Library
The melting and crystallization behavior of poly (l‐lactic acid)(PLLA; weight‐average
molecular weight= 3× 105) was studied with differential scanning calorimetry (DSC). DSC …
molecular weight= 3× 105) was studied with differential scanning calorimetry (DSC). DSC …
Relaxations of confined chains in polymer nanocomposites: glass transition properties of poly (ethylene oxide) intercalated in montmorillonite
RA Vaia, BB Sauer, OK Tse… - Journal of Polymer …, 1997 - Wiley Online Library
The relaxation behavior of poly (ethylene oxide)(PEO), intercalated in montmorillonite, a
naturally occurring mica‐type silicate, was studied by differential scanning calorimetry (DSC) …
naturally occurring mica‐type silicate, was studied by differential scanning calorimetry (DSC) …
Morphological changes during secondary crystallization and subsequent melting in poly (ether ether ketone) as studied by real time small angle X-ray scattering
In this paper, we present results of morphological studies during long time melt
crystallization and subsequent melting in poly (aryl ether ether ketone)(PEEK) …
crystallization and subsequent melting in poly (aryl ether ether ketone)(PEEK) …
Thermal analysis of poly (butylene terephthalate) for heat capacity, rigid‐amorphous content, and transition behavior
SZD Cheng, R Pan… - … Chemistry and Physics, 1988 - Wiley Online Library
Thermal analysis was performed on poly (butylene terephthalate), PBT, between 210 and
560 K. By combination of experimental heat capacities with computations with an …
560 K. By combination of experimental heat capacities with computations with an …
Giant spontaneous polarization for enhanced ferroelectric properties of biaxially oriented poly (vinylidene fluoride) by mobile oriented amorphous fractions
Poly (vinylidene fluoride)(PVDF) and its random copolymers exhibit the most distinctive
ferroelectric properties; however, their spontaneous polarization (60–105 mC m− 2) is still …
ferroelectric properties; however, their spontaneous polarization (60–105 mC m− 2) is still …
Size and confinement effects on the glass transition behavior of polystyrene/o-terphenyl polymer solutions
JY Park, GB McKenna - Physical Review B, 2000 - APS
Abstract Polystyrene (PS)/o− terphenyl (o TP) solutions confined to nanometer scale pores
were studied by differential scanning calorimetry to investigate size and confinement effects …
were studied by differential scanning calorimetry to investigate size and confinement effects …