Herein we disclose a series of phosphine-free cobalt (II)-based catalytic systems bearing a
redox non-innocent amine functionalized azo-aromatic pincer-like ligand for the synthesis of …

Four air-stable one-dimensional copper (II) coordination polymers (CP1–CP4) with azide
linkers were synthesized using tridentate NNS and NNN ligands. Single-crystal X-ray …

Air-stable square pyramidal copper (II) bromide complexes 1, 2 and 3 with NNS, N (NH) S
and NNO ligand frameworks, respectively, were synthesized and successfully utilized as …

Herein, we report azo-benzimidazole containing cobalt complexes (1–3) for alcohol
dehydrogenation-triggered C3-alkylation of indoles. In complexes 1–3, ligands are redox …

Nitroxides find application in various areas of chemistry, and a more in‐depth understanding
of factors controlling their reactivity with metal complexes is warranted to promote further …

O2, one of ideal oxidants, suffers from low solubility, low oxidizability, low selectivity and
triplet ground state in its application to organic synthesis. Biomimetic copper catalysis has …

Herein, employing pincer like cobalt (II) complexes containing redox noninnocent azo‐
benzimidazole ligand a switchable and chemodivergent catalytic cross‐coupling of primary …

An extended trisazo dipyridyl ligand, L, and its copper (I) complex,[1]+, were synthesized
and fully characterized. Complex [1]+ has five coordination geometry satisfied by ligand L. L …

Employing a series of azo-aromatic pincer-type cobalt (II) complexes, 1–5, and an imine-
based cobalt complex, 6, a highly efficient catalytic protocol for the cycloaddition of CO2 with …

In this report, a new imidazole-and amide-functionalized pincer-like Cu (II) complex (1) was
synthesized and characterized. By employing 1 and 9-azabicyclo [3.3. 1] nonane NH-Oxyl …