New advances in using Raman spectroscopy for the characterization of catalysts and catalytic reactions

C Hess - Chemical Society Reviews, 2021 - pubs.rsc.org
Gaining insight into the mode of operation of heterogeneous catalysts is of great scientific
and economic interest. Raman spectroscopy has proven its potential as a powerful …

The Role of In Situ/Operando IR Spectroscopy in Unraveling Adsorbate-Induced Structural Changes in Heterogeneous Catalysis

E Groppo, S Rojas-Buzo, S Bordiga - Chemical Reviews, 2023 - ACS Publications
Heterogeneous catalysts undergo thermal-and/or adsorbate-induced dynamic changes
under reaction conditions, which consequently modify their catalytic behavior. Hence, it is …

Uncovering the reaction mechanism behind CoO as active phase for CO2 hydrogenation

IC Have, JJG Kromwijk, M Monai, D Ferri… - Nature …, 2022 - nature.com
Transforming carbon dioxide into valuable chemicals and fuels, is a promising tool for
environmental and industrial purposes. Here, we present catalysts comprising of cobalt …

Increased Ir–Ir interaction in iridium oxide during the oxygen evolution reaction at high potentials probed by operando spectroscopy

S Czioska, A Boubnov, D Escalera-López… - ACS …, 2021 - ACS Publications
The structure of IrO2 during the oxygen evolution reaction (OER) was studied by operando X-
ray absorption spectroscopy (XAS) at the Ir L3-edge to gain insight into the processes that …

Extracting knowledge from data through catalysis informatics

AJ Medford, MR Kunz, SM Ewing, T Borders… - Acs …, 2018 - ACS Publications
Catalysis informatics is a distinct subfield that lies at the intersection of cheminformatics and
materials informatics but with distinctive challenges arising from the dynamic, surface …

Single Ru (II) ions on ceria as a highly active catalyst for abatement of NO

K Khivantsev, NR Jaegers… - Journal of the …, 2023 - ACS Publications
Atom trap** leads to catalysts with atomically dispersed Ru1O5 sites on (100) facets of
ceria, as identified by spectroscopy and DFT calculations. This is a new class of ceria-based …

Time‐resolved potential‐induced changes in Fe/N/C‐catalysts studied by in situ modulation excitation X‐ray absorption spectroscopy

K Ebner, AH Clark, VA Saveleva… - Advanced Energy …, 2022 - Wiley Online Library
To advance the widespread implementation of electrochemical energy storage and
conversion technologies, the development of inexpensive electrocatalysts is imperative. In …

Structural dynamics in Ni–Fe catalysts during CO 2 methanation–role of iron oxide clusters

MA Serrer, A Gaur, J Jelic, S Weber, C Fritsch… - Catalysis Science & …, 2020 - pubs.rsc.org
Bimetallic Ni–Fe catalysts show great potential for CO2 methanation concerning activity,
selectivity and long-term stability even under transient reaction conditions as required for …

Bifunctionality of Re Supported on TiO2 in Driving Methanol Formation in Low-Temperature CO2 Hydrogenation

N Phongprueksathat, KW Ting, S Mine, Y **g… - ACS …, 2023 - ACS Publications
Low temperature and high pressure are thermodynamically more favorable conditions to
achieve high conversion and high methanol selectivity in CO2 hydrogenation. However, low …

In Situ UV–Vis–NIR Absorption Spectroscopy and Catalysis

ML Bols, J Ma, F Rammal, D Plessers, X Wu… - Chemical …, 2024 - ACS Publications
This review highlights in situ UV–vis–NIR range absorption spectroscopy in catalysis. A
variety of experimental techniques identifying reaction mechanisms, kinetics, and structural …