Activity-based NIR fluorescent probes based on the versatile hemicyanine scaffold: design strategy, biomedical applications, and outlook

H Li, H Kim, F Xu, J Han, Q Yao, J Wang, K Pu… - Chemical Society …, 2022 - pubs.rsc.org
The discovery of a near-infrared (NIR, 650–900 nm) fluorescent chromophore hemicyanine
dye with high structural tailorability is of great significance in the field of detection …

Polyolefin thermoplastic elastomers from polymerization catalysis: Advantages, pitfalls and future challenges

G Zanchin, G Leone - Progress in Polymer Science, 2021 - Elsevier
Polyolefins have dominated materials technology over the last century and remain among
the most used materials, despite environmental problems have emerged and their public …

Nickel and palladium catalysis: Stronger demand than ever

VM Chernyshev, VP Ananikov - Acs Catalysis, 2022 - ACS Publications
Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

Polyolefins vitrimers: design principles and applications

M Ahmadi, A Hanifpour, S Ghiassinejad… - Chemistry of …, 2022 - ACS Publications
Less than 10% of plastics are recycled worldwide, among which polyolefins, which form two-
thirds of all produced polymers, are the most discarded ones. This stems from the nonpolar …

Advances on controlled chain walking and suppression of chain transfer in catalytic olefin polymerization

Y Zhang, Y Zhang, X Hu, C Wang, Z Jian - ACS Catalysis, 2022 - ACS Publications
Precise synthesis of the complex polymer structure has been long-sought. In the late
transition-metal catalyzed olefin polymerization, chain walking and chain transfer are two …

Polyethylene materials with in-chain ketones from nonalternating catalytic copolymerization

M Baur, F Lin, TO Morgen, L Odenwald, S Mecking - Science, 2021 - science.org
The world's most abundantly manufactured plastic, polyethylene, consists of inert
hydrocarbon chains. The introduction of reactive polar groups in these chains could help …

A continuing legend: the Brookhart-type α-diimine nickel and palladium catalysts

F Wang, C Chen - Polymer Chemistry, 2019 - pubs.rsc.org
The Brookhart-type α-diimine nickel and palladium catalysts are one of the most examined
systems in the field of olefin polymerization. Even after more than twenty years of extensive …

Material properties of functional polyethylenes from transition-metal-catalyzed ethylene–polar monomer copolymerization

C Tan, C Zou, C Chen - Macromolecules, 2022 - ACS Publications
Polyethylenes enjoy wide applications due to their many superior properties. The
incorporation of some polar functional groups into the otherwise nonpolar polyethylene …

Trends in the usage of bidentate phosphines as ligands in nickel catalysis

AL Clevenger, RM Stolley, J Aderibigbe… - Chemical …, 2020 - ACS Publications
A critically important process in catalysis is the formation of an active catalyst from the
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …

[HTML][HTML] Recent advances on α-diimine Ni and Pd complexes for catalyzed ethylene (Co) polymerization: A comprehensive review

R Wu, WK Wu, L Stieglitz, S Gaan, B Rieger… - Coordination Chemistry …, 2023 - Elsevier
Abstract α-Diimine Ni and Pd complexes are one of the most examined late-transition
organometallics in the application of catalyzed ethylene (co) polymerization. These …