Expanded ligands—An assembly principle for supramolecular chemistry

EC Constable - Coordination Chemistry Reviews, 2008 - Elsevier
Expanded ligands—An assembly principle for supramolecular chemistry - ScienceDirect Skip
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Crystal Structure Solid-State Cross Polarization Magic Angle Spinning 13C NMR Correlation in Luminescent d10 Metal-Organic Frameworks Constructed with the 1 …

HA Habib, A Hoffmann, HA Höppe… - Inorganic …, 2009 - ACS Publications
Hydrothermal reactions of 1, 2-bis (1, 2, 4-triazol-4-yl) ethane (btre) with copper (II), zinc (II),
and cadmium (II) salts have yielded the dinuclear complexes [Zn2Cl4 (μ2-btre) 2](1) and …

Cobalt (II) coordination polymer as a precatalyst for selective hydroboration of aldehydes, ketones, and imines

J Wu, H Zeng, J Cheng, S Zheng… - The Journal of …, 2018 - ACS Publications
Highly effective hydroboration precatalyst is developed based on a cobalt (II)-terpyridine
coordination polymer (CP). The hydroboration of ketones, aldehydes, and imines with …

Mixed-ligand coordination polymers from 1, 2-bis (1, 2, 4-triazol-4-yl) ethane and benzene-1, 3, 5-tricarboxylate: Trinuclear nickel or zinc secondary building units for …

HA Habib, J Sanchiz, C Janiak - Dalton Transactions, 2008 - pubs.rsc.org
The hydrothermal reaction of M (NO3) 2· 6H2O (M= Ni and Zn) with benzene-1, 3, 5-
tricarboxylic acid (H3btc) and 1, 2-bis (1, 2, 4-triazol-4-yl) ethane (btre) produced the mixed …

Magnetic and luminescence properties of Cu (II), Cu (II) 4O4 core, and Cd (II) mixed-ligand metal–organic frameworks constructed from 1, 2-bis (1, 2, 4-triazol-4-yl) …

HA Habib, J Sanchiz, C Janiak - Inorganica Chimica Acta, 2009 - Elsevier
The hydrothermal reaction of Cu (NO3) 2· 3H2O, Cu (ClO4) 2· 6H2O, or CdSO4· 8/3H2O
with benzene-1, 3, 5-tricarboxylic acid (H3btc) and 1, 2-bis (1, 2, 4-triazol-4-yl) ethane (btre) …

Crystal structures and solid-state CPMAS 13 C NMR correlations in luminescent zinc (II) and cadmium (II) mixed-ligand coordination polymers constructed from 1, 2 …

HA Habib, A Hoffmann, HA Höppe, C Janiak - Dalton Transactions, 2009 - pubs.rsc.org
The hydrothermal reaction of M (NO3) 2· 4H2O (M= Zn and Cd) with benzene-1, 4-
dicarboxylic acid (H2bdc) or benzene-1, 3-dicarboxylic acid (H2ip) and 1, 2-bis (1, 2, 4 …

Incorporation of switchable inorganic building blocks into heterometallic coordination polymers

MG Robb, S Brooker - Crystal Growth & Design, 2023 - ACS Publications
A new terpyridine-based ligand with a pyridyl-1, 2, 4-triazoyl bidentate pocket “out the back”
has been used to synthesize monometallic CoII, FeII, and RuII complexes where the …

Self-assembled supramolecular cages containing ruthenium (II) polypyridyl complexes

J Yang, M Bhadbhade, WA Donald… - Chemical …, 2015 - pubs.rsc.org
Substitution-inert, redox-and photo-active ruthenium (II) complexes based on 2, 2′, 6′,
2′′-terpyridine ligands were self-assembled into discrete supramolecular cages via …

Expanded ligands: bis (2, 2′: 6′, 2 ″-terpyridine carboxylic acid) ruthenium (II) complexes as metallosupramolecular analogues of dicarboxylic acids

EC Constable, EL Dunphy, CE Housecroft… - Dalton …, 2007 - pubs.rsc.org
Ligands in which multiple metal-binding domains are linked by a metal-containing moiety
rather than a conventional organic group are described as “expanded ligands”. The use of 4 …

Architectural and catalytic aspects of designer materials built using metalloligands of pyridine-2, 6-dicarboxamide based ligands

S Pachisia, R Gupta - Dalton Transactions, 2020 - pubs.rsc.org
This perspective presents the design, synthesis and crystal structures of a large number of
architectures constructed using assorted metalloligands of pyridine-2, 6-dicarboxamide …