Use of bromine and bromo-organic compounds in organic synthesis

I Saikia, AJ Borah, P Phukan - Chemical reviews, 2016 - ACS Publications
Bromination is one of the most important transformations in organic synthesis and can be
carried out using bromine and many other bromo compounds. Use of molecular bromine in …

Sustainable bromination of organic compounds: A critical review

F Sabuzi, G Pomarico, B Floris, F Valentini… - Coordination Chemistry …, 2019 - Elsevier
Considering the growing importance of sustainability in contemporary chemistry, this review
was devoted to collect and discuss papers dealing with “green” procedures for introducing …

Halogenation of aromatic compounds with N-halosuccinimides (NXS) catalysed by d-camphorsulfonic acid-BiCl 3

K Tanemura - Organic & Biomolecular Chemistry, 2024 - pubs.rsc.org
Aromatic bromination catalysed by 0.5–10 mol% of D-camphorsulfonic acid-BiCl3 with N-
bromosuccinimides (NBS) was carried out in MeCN under air conditions, and the procedure …

Artificial sugar saccharin and its derivatives: role as a catalyst

K Kaur, S Srivastava - RSC advances, 2020 - pubs.rsc.org
The primary objective of this review was to demonstrate the significance of artificial sugar
saccharin and its derivatives as catalysts for a wide variety of organic transformations. The …

Versatile Quinazolinone Synthesis: N‐Bromosaccharin‐Catalyzed Divergence in 2, 3‐Dihydroquinazolin‐4 (1H)‐one and Quinazolin‐4 (3H)‐one Formation

S Hutait, VK Maikhuri, A Kumar Pandey… - …, 2024 - Wiley Online Library
In this research, we present an innovative and eco‐friendly methodology for the synthesis of
a diverse array of 2, 3‐dihydroquinazolin‐4 (1H)‐ones, featuring the use of catalytic N …

Recent advances in the electrophilic halogenation of aromatic compounds using N-halosuccinimides (NXS)

K Tanemura - Tetrahedron Letters, 2024 - Elsevier
Halogenation of aromatic compounds is one of the most crucial reactions in modern
synthetic chemistry. Aromatic halides are important synthetic intermediates used in metal …

Dual activation with Fe (NTf2) 3 and I2: regioselective halogenation of aromatic compounds using N-halosuccinimides (NXS)

K Tanemura - Tetrahedron, 2025 - Elsevier
Halogenation of a wide range of aromatic compounds catalyzed by Fe (NTf 2) 3 in the
presence of a catalytic amount of I 2 using N-bromosuccinimide (NBS) or N …

A convenient and efficient H2SO4-promoted regioselective monobromination of phenol derivatives using N-bromosuccinimide

YQ Wu, HJ Lu, WT Zhao, HY Zhao, ZY Lin… - Synthetic …, 2020 - Taylor & Francis
Abstract A convenient, rapid H2SO4-promoted regioselective monobromination reaction
with N-bromosuccinimide was developed. The desired para-monobrominated or ortho …

New ideas for a 160 years-old reaction

G F. Mendonça, L S. de Almeida… - Current Organic …, 2015 - benthamdirect.com
Haloarenes are important chemical compounds from academic, biological, and industrial
point of view. They can usually be prepared by an electrophilic halogenation of aromatic …

Regioselective Monobromination of Phenols with KBr and ZnAl–BrO3–Layered Double Hydroxides

L Wang, C Feng, Y Zhang, J Hu - Molecules, 2020 - mdpi.com
The regioselective mono-bromination of phenols has been successfully developed with KBr
and ZnAl–BrO3−–layered double hydroxides (abbreviated as ZnAl–BrO3−–LDHs) as …