Heterogeneous catalysis

R Schlögl - Angewandte Chemie International Edition, 2015 - Wiley Online Library
A heterogeneous catalyst is a functional material that continually creates active sites with its
reactants under reaction conditions. These sites change the rates of chemical reactions of …

Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and …

JA Rodriguez, DC Grinter, Z Liu… - Chemical Society …, 2017 - pubs.rsc.org
Model metal/ceria and ceria/metal catalysts have been shown to be excellent systems for
studying fundamental phenomena linked to the operation of technical catalysts. In the last …

Ceria-based materials for thermocatalytic and photocatalytic organic synthesis

X Huang, K Zhang, B Peng, G Wang, M Muhler… - Acs …, 2021 - ACS Publications
Value-added chemicals, fuels, and pharmaceuticals synthesized by organic transformation
from raw materials via catalytic techniques have attracted enormous attention in the past few …

Raman Spectra of Polycrystalline CeO2: A Density Functional Theory Study

C Schilling, A Hofmann, C Hess… - The Journal of …, 2017 - ACS Publications
Cerium oxide is an important material for catalytic and fuel cell applications. We present an
ab initio density functional theory (DFT) study of the vibrational properties of ceria focusing …

Aerobic oxidations of light alkanes over solid metal oxide catalysts

JT Grant, JM Venegas, WP McDermott… - Chemical …, 2017 - ACS Publications
Heterogeneous metal oxide catalysts are widely studied for the aerobic oxidations of C1–C4
alkanes to form olefins and oxygenates. In this review, we outline the properties of supported …

Oxygen defects and surface chemistry of ceria: quantum chemical studies compared to experiment

J Paier, C Penschke, J Sauer - Chemical reviews, 2013 - ACS Publications
As one of the most significant rare earth oxides, ceria (CeO 2) has attracted much interest
over the past decades. In catalysis, 1, 2 CeO2 serves as a widely used support material and …

Critical literature review of the kinetics for the oxidative dehydrogenation of propane over well-defined supported vanadium oxide catalysts

CA Carrero, R Schloegl, IE Wachs… - ACS catalysis, 2014 - ACS Publications
Producing propene by the oxidative dehydrogenation of propane (ODH) has become an
attractive and feasible route for bridging the propene production-demand gap, either as a …

ZIF-67-derived Co 3 O 4@ carbon protected by oxygen-buffering CeO 2 as an efficient catalyst for boosting oxygen reduction/evolution reactions

X Li, S You, J Du, Y Dai, H Chen, Z Cai… - Journal of Materials …, 2019 - pubs.rsc.org
The synergies between transition metal oxides (bimetallic oxides) play important roles in
determining the bifunctional catalytic activity for the oxygen reduction reaction (ORR) and …

Ceria and its related materials for VOC catalytic combustion: A review

Q Wang, KL Yeung, MA Bañares - Catalysis Today, 2020 - Elsevier
Based on unique oxygen storage capacity (OSC), ceria catalysts are widely investigated for
remediation of volatile organic compounds (VOCs) over the recent decade. It is generally …

Surface chemistry and catalysis of oxide model catalysts from single crystals to nanocrystals

S Chen, F **ong, W Huang - Surface science reports, 2019 - Elsevier
Fundamental understandings of surface chemistry and catalysis of solid catalysts are of
great importance for the developments of efficient catalysts and corresponding catalytic …