Azine‐containing biaryls are ubiquitous scaffolds in many areas of chemistry, and efficient
methods for their synthesis are continually desired. Pyridine rings are prominent amongst …

This Review examines parts per million (ppm) palladium concentrations in catalytic cross-
coupling reactions and their relationship with mole percentage (mol%). Most studies in …

The synthesis of palladium nanoparticles (Pd NPs) using an aqueous extract of leaves of
Euphorbia thymifolia L. and their application in the ligand-free Stille and Hiyama cross …

The high surface area of 2D-hexagonal periodic mesoporous organosilica (PMO) containing
a phloroglucinol-diimine moiety inside the pore wall has been utilized for grafting Pd (II) at …

In this account recent developments in the Hiyama cross‐coupling reaction from 2010 up
today are presented. The most important methodology involves formation of biaryl systems …

Cross-Coupling of ArX with ArMgBr Catalyzed by N-Heterocyclic Carbene-Based Nickel
Complexes | The Journal of Organic Chemistry ACS ACS Publications C&EN CAS Find my …

Aryl ketones can be synthesized conveniently by a palladium catalyzed addition of
arylboronic acid to nitriles in aqueous triflic acid. This catalytic system was extended to the …

Among organic small molecules characterized by multifaceted behaviour, triimidazo [1, 2-a:
1′, 2′-c: 1 ″, 2 ″-e][1, 3, 5] triazine, TT, having a triazinic central ring with three …

Palladium-catalyzed Hiyama cross-coupling reactions of various arylsulfonyl hydrazides
with a wide variety of aryl silanes have been achieved in good to excellent yields under …

A well-defined NHC–Pd (II)–Im complex was proved to be an efficient catalyst for the Hiyama
reaction of a variety of aryl chlorides with aryltrimethoxysilanes. Under the optimal …