Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
The hitchhiker's guide to flow chemistry∥
Flow chemistry involves the use of channels or tubing to conduct a reaction in a continuous
stream rather than in a flask. Flow equipment provides chemists with unique control over …
stream rather than in a flask. Flow equipment provides chemists with unique control over …
The Green ChemisTREE: 20 years after taking root with the 12 principles
The field of Green Chemistry has seen many scientific discoveries and inventions during the
20 years since the 12 Principles were first published. Inspired by tree diagrams that illustrate …
20 years since the 12 Principles were first published. Inspired by tree diagrams that illustrate …
Radical hydrocarboxylation of unactivated alkenes via photocatalytic formate activation
SN Alektiar, J Han, Y Dang, CZ Rubel… - Journal of the …, 2023 - ACS Publications
Herein we disclose a strategy to promote the hydrocarboxylation of unactivated alkenes
using photochemical activation of formate salts. We illustrate that an alternative initiation …
using photochemical activation of formate salts. We illustrate that an alternative initiation …
The E factor 25 years on: the rise of green chemistry and sustainability
RA Sheldon - Green Chemistry, 2017 - pubs.rsc.org
The global impact, over the last 25 years, of the principles of green chemistry and
sustainability, and the pivotal role of the E factor concept in driving resource efficiency and …
sustainability, and the pivotal role of the E factor concept in driving resource efficiency and …
Radicals: reactive intermediates with translational potential
M Yan, JC Lo, JT Edwards… - Journal of the American …, 2016 - ACS Publications
This Perspective illustrates the defining characteristics of free radical chemistry, beginning
with its rich and storied history. Studies from our laboratory are discussed along with recent …
with its rich and storied history. Studies from our laboratory are discussed along with recent …
Photochemical approaches to complex chemotypes: applications in natural product synthesis
The use of photochemical transformations is a powerful strategy that allows for the formation
of a high degree of molecular complexity from relatively simple building blocks in a single …
of a high degree of molecular complexity from relatively simple building blocks in a single …
Pot economy and one-pot synthesis
Y Hayashi - Chemical science, 2016 - pubs.rsc.org
The one-pot synthesis of a target molecule in the same reaction vessel is widely considered
to be an efficient approach in synthetic organic chemistry. In this review, the characteristics …
to be an efficient approach in synthetic organic chemistry. In this review, the characteristics …
Organocatalytic reactions enabled by N-heterocyclic carbenes
DM Flanigan, F Romanov-Michailidis, NA White… - Chemical …, 2015 - ACS Publications
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes | Chemical Reviews ACS
ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS Publications …
ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS Publications …
Ligand-promoted palladium-catalyzed aerobic oxidation reactions
Palladium-catalyzed aerobic oxidation reactions have been the focus of industrial
application and extensive research efforts for nearly 60 years. A significant transition …
application and extensive research efforts for nearly 60 years. A significant transition …