Design of biomaterials through direct ring-opening metathesis polymerisation of functionalised cyclic alkenes

S Kobayashi, M Tanaka - Molecular Systems Design & Engineering, 2023 - pubs.rsc.org
Ring-opening metathesis polymerisation (ROMP) has become a popular method for
synthesising complex functional polymers owing to the high functional group tolerance of …

Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium− Carbene Catalysts

DL Nascimento, M Foscato, G Occhipinti… - Journal of the …, 2021 - ACS Publications
Bimolecular catalyst decomposition is a fundamental, long-standing challenge in olefin
metathesis. Emerging ruthenium–cyclic (alkyl)(amino) carbene (CAAC) catalysts, which …

Water-accelerated decomposition of olefin metathesis catalysts

CO Blanco, DE Fogg - ACS catalysis, 2023 - ACS Publications
Water is ubiquitous in olefin metathesis, at levels ranging from contaminant to cosolvent. It is
also non-benign. Water-promoted catalyst decomposition competes with metathesis, even …

Monomer Emulsified Aqueous Ring-Opening Metathesis Polymerization (ME-ROMP) for the Synthesis of Water-Soluble Molecular Bottlebrushes with a Precise …

W Hou, Y Zhou, X Yin, Y Chen, Y Shi - Macromolecules, 2023 - ACS Publications
Water-soluble molecular bottlebrushes (MBBs) with various functions and tunable
morphologies have found promising application prospects in the biorelevant field. However …

Probing Catalyst Degradation in Metathesis of Internal Olefins: Expanding Access to Amine-Tagged ROMP Polymers

SK Cormier, DE Fogg - ACS catalysis, 2023 - ACS Publications
Ruthenium-promoted ring-opening metathesis polymerization (ROMP) offers potentially
powerful routes to amine-functionalized polymers with antimicrobial, adhesive, and self …

Mechanochemical ring-opening metathesis polymerization: Development, scope, and mechano-exclusive polymer synthesis

GS Lee, HW Lee, HS Lee, T Do, JL Do, J Lim… - Chemical …, 2022 - pubs.rsc.org
Ruthenium-alkylidene initiated ring-opening metathesis polymerization has been realized
under solid-state conditions by employing a mechanochemical ball milling method. This …

Water-soluble polyphosphonate-based bottlebrush copolymers via aqueous ring-opening metathesis polymerization

DA Resendiz-Lara, S Azhdari, H Gojzewski… - Chemical …, 2023 - pubs.rsc.org
Ring-opening metathesis polymerization (ROMP) is a versatile method for synthesizing
complex macromolecules from various functional monomers. In this work, we report the …

Chemo-enzymatic synthesis of a levoglucosenone-derived bi-functional monomer and its ring-opening metathesis polymerization in the green solvent Cyrene™

S Fadlallah, AAM Peru, L Longé, F Allais - Polymer Chemistry, 2020 - pubs.rsc.org
The quite recent, yet quickly expanding, norbornene-levoglucosenone-based monomer
family was extended to include a novel bi-functional methacrylate monomer that can be …

The impact of water on Ru-catalyzed olefin metathesis: potent deactivating effects even at low water concentrations

CO Blanco, J Sims, DL Nascimento, AY Goudreault… - ACS …, 2021 - ACS Publications
Ruthenium catalysts for olefin metathesis are widely viewed as water-tolerant. Evidence is
presented, however, that even low concentrations of water cause catalyst decomposition …

Anionic Olefin Metathesis Catalysts Enable Modification of Unprotected Biomolecules in Water

CO Blanco, R Ramos Castellanos, DE Fogg - ACS catalysis, 2024 - ACS Publications
Stability problems have limited the uptake of cationic olefin metathesis catalysts in chemical
biology. Described herein are anionic catalysts that improve water-solubility, robustness …