Design of biomaterials through direct ring-opening metathesis polymerisation of functionalised cyclic alkenes
Ring-opening metathesis polymerisation (ROMP) has become a popular method for
synthesising complex functional polymers owing to the high functional group tolerance of …
synthesising complex functional polymers owing to the high functional group tolerance of …
Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium− Carbene Catalysts
DL Nascimento, M Foscato, G Occhipinti… - Journal of the …, 2021 - ACS Publications
Bimolecular catalyst decomposition is a fundamental, long-standing challenge in olefin
metathesis. Emerging ruthenium–cyclic (alkyl)(amino) carbene (CAAC) catalysts, which …
metathesis. Emerging ruthenium–cyclic (alkyl)(amino) carbene (CAAC) catalysts, which …
Water-accelerated decomposition of olefin metathesis catalysts
Water is ubiquitous in olefin metathesis, at levels ranging from contaminant to cosolvent. It is
also non-benign. Water-promoted catalyst decomposition competes with metathesis, even …
also non-benign. Water-promoted catalyst decomposition competes with metathesis, even …
Monomer Emulsified Aqueous Ring-Opening Metathesis Polymerization (ME-ROMP) for the Synthesis of Water-Soluble Molecular Bottlebrushes with a Precise …
W Hou, Y Zhou, X Yin, Y Chen, Y Shi - Macromolecules, 2023 - ACS Publications
Water-soluble molecular bottlebrushes (MBBs) with various functions and tunable
morphologies have found promising application prospects in the biorelevant field. However …
morphologies have found promising application prospects in the biorelevant field. However …
Probing Catalyst Degradation in Metathesis of Internal Olefins: Expanding Access to Amine-Tagged ROMP Polymers
Ruthenium-promoted ring-opening metathesis polymerization (ROMP) offers potentially
powerful routes to amine-functionalized polymers with antimicrobial, adhesive, and self …
powerful routes to amine-functionalized polymers with antimicrobial, adhesive, and self …
Mechanochemical ring-opening metathesis polymerization: Development, scope, and mechano-exclusive polymer synthesis
Ruthenium-alkylidene initiated ring-opening metathesis polymerization has been realized
under solid-state conditions by employing a mechanochemical ball milling method. This …
under solid-state conditions by employing a mechanochemical ball milling method. This …
Water-soluble polyphosphonate-based bottlebrush copolymers via aqueous ring-opening metathesis polymerization
Ring-opening metathesis polymerization (ROMP) is a versatile method for synthesizing
complex macromolecules from various functional monomers. In this work, we report the …
complex macromolecules from various functional monomers. In this work, we report the …
Chemo-enzymatic synthesis of a levoglucosenone-derived bi-functional monomer and its ring-opening metathesis polymerization in the green solvent Cyrene™
The quite recent, yet quickly expanding, norbornene-levoglucosenone-based monomer
family was extended to include a novel bi-functional methacrylate monomer that can be …
family was extended to include a novel bi-functional methacrylate monomer that can be …
The impact of water on Ru-catalyzed olefin metathesis: potent deactivating effects even at low water concentrations
Ruthenium catalysts for olefin metathesis are widely viewed as water-tolerant. Evidence is
presented, however, that even low concentrations of water cause catalyst decomposition …
presented, however, that even low concentrations of water cause catalyst decomposition …
Anionic Olefin Metathesis Catalysts Enable Modification of Unprotected Biomolecules in Water
Stability problems have limited the uptake of cationic olefin metathesis catalysts in chemical
biology. Described herein are anionic catalysts that improve water-solubility, robustness …
biology. Described herein are anionic catalysts that improve water-solubility, robustness …