Upgrading CO2 into multi‐carbon (C2+) compounds through the CO2 reduction reaction
(CO2RR) offers a practical approach to mitigate atmospheric CO2 while simultaneously …

Conspectus Bimetallic catalysts hold promise in tailoring the catalytic activity and selectivity
of transition metals for important chemical processes due to the synergistic coupling …

Abstract Electrocatalytic CO2‐to‐syngas (gaseous mixture of CO and H2) is a promising way
to curb excessive CO2 emission and the greenhouse gas effect. Herein, we present a …

Recently, CO2 hydrogenation had a new breakthrough resulting from the design of catalysts
to effectively activate linear CO2 with symmetry‐breaking sites. However, understanding the …

The catalytic activity and product selectivity of the electrochemical CO2 reduction reaction
(eCO2RR) depend strongly on the local microenvironment of mass diffusion at the …

In situ infrared spectroscopy is a powerful tool to obtain molecular-level information of local
environments and reaction mechanisms in solid-liquid electrochemical interfaces. The …

Although several silver-based nanoclusters have been controllably prepared and
structurally determined, their electrochemical catalytic performances have been relatively …

Ultrasmall metallic nanoclusters (NCs) protected by surface ligands represent the most
promising catalytic materials; yet understanding the structure and catalytic activity of these …

In comparison with metal nanoparticles, atomically precise nanoclusters provide a more
advantageous platform for investigating the actual active sites and reaction mechanisms of …

Accurate identification of active sites is highly desirable for elucidation of the reaction
mechanism and development of efficient catalysts. Despite the promising catalytic …