Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis

PRD Murray, JH Cox, ND Chiappini, CB Roos… - Chemical …, 2021 - ACS Publications
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Ferrocene-Mediated Photocatalytic Annulation of N-Sulfonyl Ketimines on a Polycrystalline WSe2 Semiconductor Photocatalyst

YH Lu, C Wu, JC Hou, ZL Wu, MH Zhou, XJ Huang… - ACS …, 2023 - ACS Publications
A merger of heterogeneous polycrystalline WSe2 semiconductor photocatalysis and
homogeneous ferrocene redox catalysis for the cascade radical coupling-annulation …

Electro-/photocatalytic alkene-derived radical cation chemistry: recent advances in synthetic applications

MJ Luo, Q **ao, JH Li - Chemical Society Reviews, 2022 - pubs.rsc.org
Alkene-derived radical cations are versatile reactive intermediates and have been widely
applied in the construction of complex functionalized molecules and cyclic systems for …

Recent advances in electrochemical oxidative cross-coupling with hydrogen evolution involving radicals

Y Yuan, J Yang, A Lei - Chemical Society Reviews, 2021 - pubs.rsc.org
Oxidative cross-coupling has developed into a robust method for carbon–carbon (C–C),
carbon–heteroatom (C–X), and heteroatom–heteroatom (X–Y) bond formation. Despite …

Recent advances in organic electrosynthesis employing transition metal complexes as electrocatalysts

C Ma, P Fang, ZR Liu, SS Xu, K Xu, X Cheng, A Lei… - Science Bulletin, 2021 - Elsevier
Organic electrosynthesis has been widely used as an environmentally conscious alternative
to conventional methods for redox reactions because it utilizes electric current as a traceless …

Ferrocene/air double-mediated FeTiO3-photocatalyzed semi-heterogeneous annulation of quinoxalin-2 (1H)-ones in EtOH/H2O

WT Ouyang, HT Ji, J Jiang, C Wu, JC Hou… - Chemical …, 2023 - pubs.rsc.org
With both ferrocene and air as the redox catalysts, for the first time, the low-cost natural
ilmenite (FeTiO3) was successfully used for photocatalytic bond formations. Under the …

Toward effective electrocatalytic C–N coupling for the synthesis of organic nitrogenous compounds using CO2 and biomass as carbon sources

H Jiang, X Wu, H Zhang, Q Yan, H Li, T Ma, S Yang - SusMat, 2023 - Wiley Online Library
Thermochemical conversion of fossil resources into fuels, chemicals, and materials has
rapidly increased atmospheric CO2 levels, hindering global efforts toward achieving carbon …

Chemistry with electrochemically generated N-centered radicals

P **ong, HC Xu - Accounts of Chemical Research, 2019 - ACS Publications
Conspectus N-centered radicals are versatile reaction intermediates that can react with
various π systems to construct C–N bonds. Current methods for generating N-centered …

Electrochemical oxidative cross-coupling with hydrogen evolution reactions

Y Yuan, A Lei - Accounts of Chemical Research, 2019 - ACS Publications
Conspectus Oxidative cross-coupling has proved to be one of the most straightforward
strategies for forming carbon–carbon and carbon–heteroatom bonds from easily available …