Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …
anisotropy of mono-nuclear transition metal complexes in various coordination …
Single-chain magnets: beyond the Glauber model
Single-chain magnets (SCMs) are one-dimensional (1D) slow-relaxing magnetic chains with
interesting fundamental properties and applications, such as information storage. The …
interesting fundamental properties and applications, such as information storage. The …
Zinc–organic battery with a wide operation‐temperature window from− 70 to 150° C
Aqueous zinc (Zn) batteries have been considered as promising candidates for grid‐scale
energy storage. However, their cycle stability is generally limited by the structure collapse of …
energy storage. However, their cycle stability is generally limited by the structure collapse of …
Nanoporous cobalt (II) MOF exhibiting four magnetic ground states and changes in gas sorption upon post-synthetic modification
MH Zeng, Z Yin, YX Tan, WX Zhang… - Journal of the …, 2014 - ACS Publications
We present the syntheses, structural characterization, gas sorption, I2 uptake, and magnetic
properties of a double-walled porous metal–organic framework,[CoII3 (lac) 2 (pybz) 2] …
properties of a double-walled porous metal–organic framework,[CoII3 (lac) 2 (pybz) 2] …
Field-induced slow magnetic relaxation in a six-coordinate mononuclear cobalt (II) complex with a positive anisotropy
The novel mononuclear Co (II) complex cis-[CoII (dmphen) 2 (NCS) 2]· 0.25 EtOH
(1)(dmphen= 2, 9-dimethyl-1, 10-phenanthroline) features a highly rhombically distorted …
(1)(dmphen= 2, 9-dimethyl-1, 10-phenanthroline) features a highly rhombically distorted …
Single-molecule magnet engineering: building-block approaches
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …
the constituent metal ion building blocks. Although this general approach does not seem to …
Single‐chain magnet based on cobalt (II) thiocyanate as XXZ spin chain
The cobalt (II) in [Co (NCS) 2 (4‐methoxypyridine) 2] n are linked by pairs of thiocyanate
anions into linear chains. In contrast to a previous structure determination, two …
anions into linear chains. In contrast to a previous structure determination, two …
[ReF6]2−: A Robust Module for the Design of Molecule‐Based Magnetic Materials
A facile synthesis of the [ReF6] 2− ion and its use as a building block to synthesize magnetic
systems are reported. Using dc and ac magnetic susceptibility measurements, INS and EPR …
systems are reported. Using dc and ac magnetic susceptibility measurements, INS and EPR …
Structural and magnetic properties of some lanthanide (Ln= Eu (III), Gd (III) and Nd (III)) cyanoacetate polymers: field-induced slow magnetic relaxation in the Gd and …
The lanthanide (III) cyanoacetate complexes of the formula {[Ln2 (CNCH2COO) 6 (H2O) 4]·
2H2O} n, where Ln= Eu (1), Gd (2), Nd (3), have been prepared and characterized by X-ray …
2H2O} n, where Ln= Eu (1), Gd (2), Nd (3), have been prepared and characterized by X-ray …
Enhanced Single‐Chain Magnet Behavior via Anisotropic Exchange in a Cyano‐Bridged MoIII–MnII Chain
Anisotropic magnetic exchange is of great value for the design of high performance
molecular nanomagnets. In the present work, enhanced single‐chain magnet (SCM) …
molecular nanomagnets. In the present work, enhanced single‐chain magnet (SCM) …