Recent Advances and Prospects in High‐Performance Bio‐Based Phthalonitrile Resins

BA Bulgakov, US Schubert - Advanced Functional Materials, 2024 - Wiley Online Library
Phthalontirile resins are renowned as the most heat‐resistant polymeric materials and
exhibit exceptional performance under harsh conditions. Consequently, phthalonitrile …

Kinetics of the oxidative aging of phthalonitrile resins and their effects on the mechanical properties of thermosets

MS Lobanova, VV Aleshkevich, MY Yablokova… - Thermochimica …, 2023 - Elsevier
The process of thermal oxidation decomposition of phthalonitrile resins which had been post-
cured at various temperatures (603 K, 623 K and 648 K) was studied using dynamic and …

Fast curing phthalonitrile modified novolac resin: Synthesis, curing study and preparation of carbon and glass fibric composites

DI Poliakova, OS Morozov, SS Nechausov… - Reactive and Functional …, 2022 - Elsevier
Phthalonitrile modified novolac (PNN) was synthesized in aim to develop a fast-curing resin
for hot-pressing processing and characterized by NMR to confirm a full substitution of …

Heat-resistant phthalonitrile-based resins for 3D printing via VAT photopolymerization

S Nechausov, A Aleksanova, O Morozov… - ACS Applied Polymer …, 2022 - ACS Publications
In this study, a maleimide/phthalonitrile bifunctional monomer PNB-M was used in vat
photopolymerization via the maleimide group to obtain phthalonitrile-containing polymers …

Fast-Processable Non-Flammable phthalonitrile-modified novolac/carbon and glass fiber composites

D Poliakova, O Morozov, Y Lipatov, A Babkin… - Polymers, 2022 - mdpi.com
Phthalonitrile resins (PN) are known for their incredible heat resistance and at the same time
poor processability. Common curing cycle of the PN includes dozens hours of heating at …

Deep learning model for precise prediction and design of low-melting point phthalonitrile monomers

R Lu, Y Han, J Hu, D Xu, Z Zhong, H Zhou… - Chemical Engineering …, 2024 - Elsevier
Phthalonitrile is a widely applied resin due to its outstanding high-temperature resistance
and versatility. However, the high melting point of its monomer limits its range of …

Effect of post‐curing temperature on the retention of mechanical strength of phthalonitrile thermosets and composites after a long‐term thermal oxidative aging

M Lobanova, V Aleshkevich, A Babkin… - Polymer …, 2023 - Wiley Online Library
This work concerns the thermal‐oxidative aging behavior of phthalonitrile thermosets and
composites at 280–350° C. The easy‐to‐process resin containing bis (3‐[3, 4 …

Easy processable tris-phthalonitrile based resins and carbon fabric reinforced composites fabricated by vacuum infusion

MV Yakovlev, ME Kuchevskaia, VE Terekhov… - Materials Today …, 2022 - Elsevier
Easy-processable phthalonitrile resins were prepared from tris-phthalonitrile phosphate
monomer TPP (tris (3-(3, 4-dicyanophenoxy) phenyl) phosphate), bis-phthalonitrile RP (bis …

Characterization of Eumelanin as an Additive in High‐Temperature Phthalonitrile‐Based Resin Blends

JL Dysart, JD Wolfgang, AD Smith… - Macromolecular …, 2023 - Wiley Online Library
Bio‐manufactured eumelanin is investigated as a sustainable high‐char carbon additive for
use with moldable high temperature resins. Blends of Bisphenol A poly‐ether‐ether‐ketone …

The nano-clay effect on the improvement of the thermal, flammability, and mechanical behavior of epoxy/glass fiber/ATH hybrid composites

H Shahrajabian, H Vaezzadeh - Journal of Composite …, 2024 - journals.sagepub.com
More than 50% of the flame retardants used in the polymer and plastic industries are metal
hydroxides. Among them, aluminum trihydroxide (ATH) is the most widely used due to its low …