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Operando Electron Microscopy of Catalysts: The Missing Cornerstone in Heterogeneous Catalysis Research?
Heterogeneous catalysis in thermal gas-phase and electrochemical liquid-phase chemical
conversion plays an important role in our modern energy landscape. However, many of the …
conversion plays an important role in our modern energy landscape. However, many of the …
The reverse water gas shift reaction: a process systems engineering perspective
M González-Castaño, B Dorneanu… - Reaction Chemistry & …, 2021 - pubs.rsc.org
The catalytic reduction of CO2 into value-added products has been considered a compelling
solution for alleviating global warming and energy crises. The reverse water gas shift …
solution for alleviating global warming and energy crises. The reverse water gas shift …
Geminal-atom catalysis for cross-coupling
Single-atom catalysts (SACs) have well-defined active sites, making them of potential
interest for organic synthesis,,–. However, the architecture of these mononuclear metal …
interest for organic synthesis,,–. However, the architecture of these mononuclear metal …
Role of Defects in the Interplay between Adsorbate Evolving and Lattice Oxygen Mechanisms of the Oxygen Evolution Reaction in RuO2 and IrO2
The mechanistic interplay between the oxygen evolution reaction (OER) and material
degradation during water electrolysis is not yet well understood even for the most studied …
degradation during water electrolysis is not yet well understood even for the most studied …
Single-atom catalysts designed and prepared by the atomic layer deposition technique
The atomic layer deposition (ALD) technique allows the synthesis of materials at the atomic
scale to be controlled. ALD has been adapted to design and prepare single-atom catalysts …
scale to be controlled. ALD has been adapted to design and prepare single-atom catalysts …
The Role of In Situ/Operando IR Spectroscopy in Unraveling Adsorbate-Induced Structural Changes in Heterogeneous Catalysis
Heterogeneous catalysts undergo thermal-and/or adsorbate-induced dynamic changes
under reaction conditions, which consequently modify their catalytic behavior. Hence, it is …
under reaction conditions, which consequently modify their catalytic behavior. Hence, it is …
A heterogeneous single-atom palladium catalyst surpassing homogeneous systems for Suzuki coupling
Palladium-catalysed cross-coupling reactions, central tools in fine-chemical synthesis,
predominantly employ soluble metal complexes despite recognized challenges with product …
predominantly employ soluble metal complexes despite recognized challenges with product …
In situ manipulation of the active Au-TiO2 interface with atomic precision during CO oxidation
The interface between metal catalyst and support plays a critical role in heterogeneous
catalysis. An epitaxial interface is generally considered to be rigid, and tuning its intrinsic …
catalysis. An epitaxial interface is generally considered to be rigid, and tuning its intrinsic …
Unravelling structure sensitivity in CO2 hydrogenation over nickel
Continuous efforts in the field of materials science have allowed us to generate smaller and
smaller metal nanoparticles, creating new opportunities to understand catalytic properties …
smaller metal nanoparticles, creating new opportunities to understand catalytic properties …
Experimental characterization techniques for plasmon-assisted chemistry
Plasmon-assisted chemistry is the result of a complex interplay between electromagnetic
near fields, heat and charge transfer on the nanoscale. The disentanglement of their roles is …
near fields, heat and charge transfer on the nanoscale. The disentanglement of their roles is …